Mechanochemical lithiation of layered polysilane

Lithiated polysilane was synthesized by the mechanochemical reaction of layered polysilane with metallic lithium. The resulting dark green powder formed a Si-Li bond on the surface and demonstrated electroconductivity.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-09, Vol.50 (68), p.9761-9764
Main Authors: Ohashi, Masataka, Nakano, Hideyuki, Morishita, Tetsuya, Spencer, Michelle J S, Ikemoto, Yuka, Yogi, Chihiro, Ohta, Toshiaki
Format: Article
Language:English
Subjects:
Chemical bonds
Lithium
Mechanochemistry
Polysilanes
Synthesis (chemistry)
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Description
Summary:Lithiated polysilane was synthesized by the mechanochemical reaction of layered polysilane with metallic lithium. The resulting dark green powder formed a Si-Li bond on the surface and demonstrated electroconductivity.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc03850a