The ring opening reaction of 1,3-dithiol-2-one systems is fully reversible

The deprotection of a common precursor moiety in dithiolene chemistry was discovered to be fully reversible, which, besides being relevant for researchers working in very different fields with these non-innocent ligand systems, may even have an impact on CO2 housekeeping, as the deprotected ligand a...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-09, Vol.50 (70), p.10102-10104
Main Authors: Ghosh, Ashta Chandra, Reinhardt, Jakob Klaus, Kindermann, Markus Karl, Schulzke, Carola
Format: Article
Language:English
Subjects:
Carbon dioxide
Ligands
Magnetic Resonance Spectroscopy - methods
Precursors
Ring opening
Toluene - analogs & derivatives
Toluene - chemical synthesis
Toluene - metabolism
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Summary:The deprotection of a common precursor moiety in dithiolene chemistry was discovered to be fully reversible, which, besides being relevant for researchers working in very different fields with these non-innocent ligand systems, may even have an impact on CO2 housekeeping, as the deprotected ligand acts as an efficient trap.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc04414b