Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis

The ruthenium-catalyzed oxidative allylation of aromatic and α,β-unsaturated carboxamides with allylic carbonates is described. These transformations proceed readily with complete linear γ-selectivity of substituted allylic carbonates.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (77), p.11303-11306
Main Authors: Kim, Mirim, Sharma, Satyasheel, Mishra, Neeraj Kumar, Han, Sangil, Park, Jihye, Kim, Minyoung, Shin, Youngmi, Kwak, Jong Hwan, Han, Sang Hoon, Kim, In Su
Format: Article
Language:English
Subjects:
Allyl compounds
Allyl Compounds - chemical synthesis
Benzamides - chemical synthesis
Carbonates
Carbonates - chemical synthesis
Catalysis
Chemical reactions
Palladium - chemistry
Pyrrolidines - chemical synthesis
Rhodium - chemistry
Ruthenium
Ruthenium - chemistry
Transformations
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Description
Summary:The ruthenium-catalyzed oxidative allylation of aromatic and α,β-unsaturated carboxamides with allylic carbonates is described. These transformations proceed readily with complete linear γ-selectivity of substituted allylic carbonates.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc03354j