Antimony-dependent expansion for the Keggin heteropolyniobate family

Nine new Sb-bicapped α-Keggin-type heteropolyoxoniobates (HPNb) were synthesized under hydrothermal conditions. Among them, the As-centered HPNb was never reported before, and the two dimer compounds are the biggest isolated HPNbs at present.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (15), p.3091-3093
Main Authors: Zhang, Zhe-Yu, Peng, Jun, Shi, Zhen-Yu, Zhou, Wan-Li, Khan, Shifa Ullah, Liu, Hong-Sheng
Format: Article
Language:English
Subjects:
Dimers
Synthesis
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Summary:Nine new Sb-bicapped α-Keggin-type heteropolyoxoniobates (HPNb) were synthesized under hydrothermal conditions. Among them, the As-centered HPNb was never reported before, and the two dimer compounds are the biggest isolated HPNbs at present.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc09612f