New structural type in the chemistry of bismuth(III) polynuclear halide complexes: Synthesis and crystal structure of (H sub(3)O) sub(3)(diquat) sub(6){[BiBr sub(5)] } sub(6)[BiBr sub(6)] times 2H sub(2)O

Complex (H sub(3)O) sub(3)(diquat) sub(6){[BiBr sub(5)] } sub(6)[BiBr sub(6)] times 2H sub(2)O (I) has been prepared by the reaction between [BiBr sub(6)] super(3-) and diaqua(1,1'-diethylene-2,2'-bipyridynium dibromide) in 2 M HBr and has been characterized by X-ray diffraction. The anion...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2016-08, Vol.61 (8), p.958-963
Main Authors: Adonin, SA, Gorokh, I D, Samsonenko, D G, Korol'kov, I V, Sokolov, M N, Fedin, V P
Format: Article
Language:English
Subjects:
Anions
Building components
Crystal structure
Dibromides
Halides
Ligands
Synthesis (chemistry)
X ray diffraction
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Summary:Complex (H sub(3)O) sub(3)(diquat) sub(6){[BiBr sub(5)] } sub(6)[BiBr sub(6)] times 2H sub(2)O (I) has been prepared by the reaction between [BiBr sub(6)] super(3-) and diaqua(1,1'-diethylene-2,2'-bipyridynium dibromide) in 2 M HBr and has been characterized by X-ray diffraction. The anionic part of compound I is formed by coordination polymeric anions {[BiBr sub(5)] super(-)} sub( n ) built of {BiBr sub(6)} octahedral blocks, which are joined by the mu super(2)-bridge bromide ligands into infinite zigzag chains. The resulting complex belongs to new structural type among bismuth halide complexes.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023616080027