On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity

We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (82), p.12281-12284
Main Authors: Geeson, M B, Jupp, A R, McGrady, J E, Goicoechea, J M
Format: Article
Language:English
Subjects:
Basicity
Electronic properties
Ligands
Phosphines
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Description
Summary:We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc06094f