Nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes

A nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes using removable 2-(pyridine-2-yl)-isopropylamine as a directing group is described. This strategy provides an efficient access to valuable aryl sulfides with ample substrate scope and a high degree of functional...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (17), p.3582-3585
Main Authors: Yang, Ke, Wang, Yuqi, Chen, Xinyong, Kadi, Adnan A, Fun, Hoong-Kun, Sun, Hao, Zhang, Yan, Lu, Hongjian
Format: Article
Language:English
Subjects:
Aromatic compounds
Benzene Derivatives - chemistry
Benzoic Acid - chemistry
Catalysis
Functional groups
Molecular Structure
Nickel
Nickel - chemistry
Strategy
Substrates
Sulfides
Sulfides - chemical synthesis
Sulfides - chemistry
Tolerances
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes using removable 2-(pyridine-2-yl)-isopropylamine as a directing group is described. This strategy provides an efficient access to valuable aryl sulfides with ample substrate scope and a high degree of functional group tolerance.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc10431e