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Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR
Pulsed electron paramagnetic resonance (EPR) spectroscopy is gaining increasing importance as a complementary biophysical technique in structural biology. Here, we describe the synthesis, optimisation, and EPR titration studies of a spin-labelled terpyridine Zn(II) complex serving as a small-molecul...
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| Published in: | Chemical communications (Cambridge, England) England), 2015-03, Vol.51 (25), p.5257-5260 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c356t-1456624cb4b0174e89411f103ee19c76eb871d32c227048339552ce0cb3a7dfa3 |
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| cites | cdi_FETCH-LOGICAL-c356t-1456624cb4b0174e89411f103ee19c76eb871d32c227048339552ce0cb3a7dfa3 |
| container_end_page | 5260 |
| container_issue | 25 |
| container_start_page | 5257 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 51 |
| creator | Ackermann, K Giannoulis, A Cordes, D B Slawin, A M Z Bode, B E |
| description | Pulsed electron paramagnetic resonance (EPR) spectroscopy is gaining increasing importance as a complementary biophysical technique in structural biology. Here, we describe the synthesis, optimisation, and EPR titration studies of a spin-labelled terpyridine Zn(II) complex serving as a small-molecule model system for tuneable dimerisation. |
| doi_str_mv | 10.1039/c4cc08656b |
| format | article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2015-03, Vol.51 (25), p.5257-5260 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Biology Biomimetic Materials - chemical synthesis Biomimetic Materials - chemistry Biomimetics Crystallography, X-Ray Electron paramagnetic resonance Electron Spin Resonance Spectroscopy Mathematical models Models, Molecular Molecular Structure Optimization Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Pyridines - chemistry Spectroscopy Synthesis Titration Zinc - chemistry |
| title | Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR |
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