Thermally stable phthalonitrile matrixes containing siloxane fragments

New low-melting phthalonitrile monomers suitable for the production of high-temperature matrixes for polymer composite materials are synthesized. After the introduction of siloxane bridges into a monomer, the glass-transition temperature decreases to–1–27°С, depending on the type of substituent at t...

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Bibliographic Details
Published in:Polymer science. Series B 2016-05, Vol.58 (3), p.298-306
Main Authors: Babkin, A. V., Zodbinov, E. B., Bulgakov, B. A., Kepman, A. V., Avdeev, V. V.
Format: Article
Language:English
Subjects:
Argon
Chemistry
Chemistry and Materials Science
Combustion
Composite materials
Glass transition temperature
High temperature
Monomers
Polymer matrix composites
Polymer Sciences
Polymers
Resins
Silicon
Silicon compounds
Siloxanes
Synthesis
Thermal stability
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Summary:New low-melting phthalonitrile monomers suitable for the production of high-temperature matrixes for polymer composite materials are synthesized. After the introduction of siloxane bridges into a monomer, the glass-transition temperature decreases to–1–27°С, depending on the type of substituent at the silicon atom. These compounds are found to be sufficiently hydrolytically stable, despite the presence of sensitive siloxane bonds. The cured resin retain properties featured to the class of phthalonitriles, such as a high onset tеmperature of degradation (>530°С in argon), a high heat deflection temperature (>420°С), and char yield. The considered compounds make it possible to widen the temperature window for processing of phthalonitrile resins without any change in the properties of the final material.
ISSN:1560-0904
1555-6123
DOI:10.1134/S1560090416030027