Chemical plasticizing of polyacrylonitrile by copolymerization with other monomers

Chemical plasticizing of polyacrylonitrile (PAN) was carried out by copolymerization of acrylonitrile with other monomers such as methacrylic esters: vinyl acetate, vinyl benzoate, styrene, and butyl vinyl ether. We identified and analyzed parameters of PAN, polymer modifiers and their macromolecule...

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Bibliographic Details
Published in:Molecular Crystals and Liquid Crystals 2016-11, Vol.640 (1), p.98-105
Main Authors: Manchenko, O., Iukhymenko, N., Nizhnik, V.
Format: Article
Language:English
Subjects:
Benzoates
Chemical industry
chemical plasticizing
Copolymerization
Copolymers
methacrylic esters
Monomers
Parameter modification
polyacrylonitrile
Polyacrylonitriles
polymer modifiers
Polymerization
Polymethyl methacrylate
Polymethyl methacrylates
Polystyrene resins
Styrenes
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Summary:Chemical plasticizing of polyacrylonitrile (PAN) was carried out by copolymerization of acrylonitrile with other monomers such as methacrylic esters: vinyl acetate, vinyl benzoate, styrene, and butyl vinyl ether. We identified and analyzed parameters of PAN, polymer modifiers and their macromolecules as polymethyl methacrylate (PMMA), polybutyl methacrylate (PBMA), polyvinyl acetate (PVA), polyvinyl benzoate (PVB), polystyrene (PS), and polyvinyl butyl ether (PVBE). This article reports the method of chemical plasticizing of polar chain polymer (PAN) by the reduction of polar parts and tuning the dipole moment value of the copolymer links.
ISSN:1542-1406
1563-5287
1527-1943
DOI:10.1080/15421406.2016.1255521