Loading…
Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct
The solid and solution state structure of the vanadium(ii) N-heterocyclic silylene (NHSi) complex, [( IPr)V(Cp) ] (1) is reported ( IPr: 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene). The electronic structure of 1 is probed using a combination of magnetic measurements, EPR...
Saved in:
Published in: | Dalton transactions : an international journal of inorganic chemistry 2017-08, Vol.46 (30), p.9740-9744 |
---|---|
Main Authors: | , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | The solid and solution state structure of the vanadium(ii) N-heterocyclic silylene (NHSi) complex, [(
IPr)V(Cp)
] (1) is reported (
IPr: 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene). The electronic structure of 1 is probed using a combination of magnetic measurements, EPR spectroscopy and computational studies. The V-Si bond strength and complex forming mechanism between vanadocene and an NHSi ligand is elucidated using computational methods. |
---|---|
ISSN: | 1477-9226 1477-9234 |
DOI: | 10.1039/c7dt01226h |