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Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct

The solid and solution state structure of the vanadium(ii) N-heterocyclic silylene (NHSi) complex, [( IPr)V(Cp) ] (1) is reported ( IPr: 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene). The electronic structure of 1 is probed using a combination of magnetic measurements, EPR...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2017-08, Vol.46 (30), p.9740-9744
Main Authors: Hänninen, Mikko M, Baldansuren, Amgalanbaatar, Pugh, Thomas
Format: Article
Language:English
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Summary:The solid and solution state structure of the vanadium(ii) N-heterocyclic silylene (NHSi) complex, [( IPr)V(Cp) ] (1) is reported ( IPr: 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene). The electronic structure of 1 is probed using a combination of magnetic measurements, EPR spectroscopy and computational studies. The V-Si bond strength and complex forming mechanism between vanadocene and an NHSi ligand is elucidated using computational methods.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt01226h