Synthesis of Functionalized Indenones via Rh-Catalyzed C–H Activation Cascade Reaction

An efficient and expeditious protocol for the synthesis of diverse difunctionalized indenones through rhodium-catalyzed C–H activation and multistep cascade reaction of benzimidates and alkenes has been developed. The transformation involves the cleavage and formation of multiple bonds in one pot un...

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Bibliographic Details
Published in:Organic letters 2017-05, Vol.19 (10), p.2588-2591
Main Authors: Lv, Ningning, Chen, Zhengkai, Liu, Yue, Liu, Zhanxiang, Zhang, Yuhong
Format: Article
Language:English
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Summary:An efficient and expeditious protocol for the synthesis of diverse difunctionalized indenones through rhodium-catalyzed C–H activation and multistep cascade reaction of benzimidates and alkenes has been developed. The transformation involves the cleavage and formation of multiple bonds in one pot under mild reaction conditions, and Mn­(OAc)2 plays an important role in the reaction.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.7b00906