Palladium-Catalyzed C(sp2)–H Acetoxylation via Electrochemical Oxidation

Palladium-catalyzed arene C­(sp2)–H acetoxylation has emerged as a powerful tool to construct a carbon–oxygen (C–O) bond. However, the requirement of stoichiometric chemical oxidants for this transformation possesses a significant disadvantage. To solve this fundamental problem, we now report an ano...

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Bibliographic Details
Published in:Organic letters 2017-06, Vol.19 (11), p.2905-2908
Main Authors: Li, Yi-Qian, Yang, Qi-Liang, Fang, Ping, Mei, Tian-Sheng, Zhang, Dayong
Format: Article
Language:English
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Summary:Palladium-catalyzed arene C­(sp2)–H acetoxylation has emerged as a powerful tool to construct a carbon–oxygen (C–O) bond. However, the requirement of stoichiometric chemical oxidants for this transformation possesses a significant disadvantage. To solve this fundamental problem, we now report an anodic oxidation strategy to achieve arene C­(sp2)–H acetoxylation.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.7b01138