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Aggregation-induced emission: mechanistic study of the clusteroluminescence of tetrathienylethene
In this work we have investigated the aggregation-induced emission (AIE) behaviour of 1,1,2,2-tetra(thiophen-2-yl)ethene (tetrathienylethene, TTE). The semi-locked and fully-locked derivatives (sl-TTE and fl-TTE) have been synthesized to better understand the mechanism behind the solid state photolu...
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Published in: | Chemical science (Cambridge) 2017-04, Vol.8 (4), p.2629-2639 |
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creator | Viglianti, Lucia Leung, Nelson L C Xie, Ni Gu, Xinggui Sung, Herman H Y Miao, Qian Williams, Ian D Licandro, Emanuela Tang, Ben Zhong |
description | In this work we have investigated the aggregation-induced emission (AIE) behaviour of 1,1,2,2-tetra(thiophen-2-yl)ethene (tetrathienylethene, TTE). The semi-locked and fully-locked derivatives (sl-TTE and fl-TTE) have been synthesized to better understand the mechanism behind the solid state photoluminescence of TTE. TTE is a typical AIEgen and its luminescence can be explained through the mechanistic understanding of the restriction of intramolecular motions (RIM). The emissive behaviour of TTE in the THF/water aggregates and crystal state have also been studied, revealing a remarkable red-shift of 35 nm. A similar red-shift emission of 37 nm from the THF/water aggregates to the crystal state is also observed for (
)-1,2-di(thiophen-2-yl)ethene (
-dithienylethene, DTE). Crystal analysis has revealed that the emission red-shifts are ascribable to the presence of strong sulfur-sulfur (S···S) intra- and intermolecular interactions that are as close as 3.669 Å for TTE and 3.679 Å for DTE. These heteroatom interactions could help explain the photoluminescence of non-conventional luminophores as well as the luminescence of non-conjugated biomacromolecules. |
doi_str_mv | 10.1039/c6sc05192h |
format | article |
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)-1,2-di(thiophen-2-yl)ethene (
-dithienylethene, DTE). Crystal analysis has revealed that the emission red-shifts are ascribable to the presence of strong sulfur-sulfur (S···S) intra- and intermolecular interactions that are as close as 3.669 Å for TTE and 3.679 Å for DTE. These heteroatom interactions could help explain the photoluminescence of non-conventional luminophores as well as the luminescence of non-conjugated biomacromolecules.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/c6sc05192h</identifier><identifier>PMID: 28553498</identifier><language>eng</language><publisher>England</publisher><subject>Aggregates ; Behavior ; Crystals ; Derivatives ; Emission ; Emission analysis ; Luminescence ; Photoluminescence</subject><ispartof>Chemical science (Cambridge), 2017-04, Vol.8 (4), p.2629-2639</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-1ae052b76ec5ef9e73538fa95b489499659ecc6240838e30bb7f8573e54ba44c3</citedby><cites>FETCH-LOGICAL-c356t-1ae052b76ec5ef9e73538fa95b489499659ecc6240838e30bb7f8573e54ba44c3</cites><orcidid>0000-0001-9933-6548 ; 0000-0001-8493-0886 ; 0000-0002-0293-964X ; 0000-0002-3370-0332 ; 0000-0003-3949-9622 ; 0000-0003-0168-9295</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28553498$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Viglianti, Lucia</creatorcontrib><creatorcontrib>Leung, Nelson L C</creatorcontrib><creatorcontrib>Xie, Ni</creatorcontrib><creatorcontrib>Gu, Xinggui</creatorcontrib><creatorcontrib>Sung, Herman H Y</creatorcontrib><creatorcontrib>Miao, Qian</creatorcontrib><creatorcontrib>Williams, Ian D</creatorcontrib><creatorcontrib>Licandro, Emanuela</creatorcontrib><creatorcontrib>Tang, Ben Zhong</creatorcontrib><title>Aggregation-induced emission: mechanistic study of the clusteroluminescence of tetrathienylethene</title><title>Chemical science (Cambridge)</title><addtitle>Chem Sci</addtitle><description>In this work we have investigated the aggregation-induced emission (AIE) behaviour of 1,1,2,2-tetra(thiophen-2-yl)ethene (tetrathienylethene, TTE). The semi-locked and fully-locked derivatives (sl-TTE and fl-TTE) have been synthesized to better understand the mechanism behind the solid state photoluminescence of TTE. TTE is a typical AIEgen and its luminescence can be explained through the mechanistic understanding of the restriction of intramolecular motions (RIM). The emissive behaviour of TTE in the THF/water aggregates and crystal state have also been studied, revealing a remarkable red-shift of 35 nm. A similar red-shift emission of 37 nm from the THF/water aggregates to the crystal state is also observed for (
)-1,2-di(thiophen-2-yl)ethene (
-dithienylethene, DTE). Crystal analysis has revealed that the emission red-shifts are ascribable to the presence of strong sulfur-sulfur (S···S) intra- and intermolecular interactions that are as close as 3.669 Å for TTE and 3.679 Å for DTE. These heteroatom interactions could help explain the photoluminescence of non-conventional luminophores as well as the luminescence of non-conjugated biomacromolecules.</description><subject>Aggregates</subject><subject>Behavior</subject><subject>Crystals</subject><subject>Derivatives</subject><subject>Emission</subject><subject>Emission analysis</subject><subject>Luminescence</subject><subject>Photoluminescence</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFkU9PwzAMxSMEYtPYhQ-AekRIhbRO0oTbVAFDmsQBOFdp6m5B_TOS9LBvT9nGrvhiy_7pSc-PkOuE3icU1IMR3lCeqHRzRqYpZUksOKjz05zSCZl7_0XHAkh4ml2SSSo5B6bklOjFeu1wrYPtu9h21WCwirC13o-Lx6hFs9Gd9cGayIeh2kV9HYUNRqYZfEDXN0NrO_QGO4P7Gwanw8Zit2twBDu8Ihe1bjzOj31GPp-fPvJlvHp7ec0Xq9gAFyFONFKelplAw7FWmAEHWWvFSyYVU0pwhcaIlFEJEoGWZVZLngFyVmrGDMzI7UF36_rvAX0oRhcGm0Z32A--SBQFBlmWif9RqUAqzmU6oncH1Ljee4d1sXW21W5XJLT4DaDIxXu-D2A5wjdH3aFssTqhf--GH_Y9gaY</recordid><startdate>20170401</startdate><enddate>20170401</enddate><creator>Viglianti, Lucia</creator><creator>Leung, Nelson L C</creator><creator>Xie, Ni</creator><creator>Gu, Xinggui</creator><creator>Sung, Herman H Y</creator><creator>Miao, Qian</creator><creator>Williams, Ian D</creator><creator>Licandro, Emanuela</creator><creator>Tang, Ben Zhong</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-9933-6548</orcidid><orcidid>https://orcid.org/0000-0001-8493-0886</orcidid><orcidid>https://orcid.org/0000-0002-0293-964X</orcidid><orcidid>https://orcid.org/0000-0002-3370-0332</orcidid><orcidid>https://orcid.org/0000-0003-3949-9622</orcidid><orcidid>https://orcid.org/0000-0003-0168-9295</orcidid></search><sort><creationdate>20170401</creationdate><title>Aggregation-induced emission: mechanistic study of the clusteroluminescence of tetrathienylethene</title><author>Viglianti, Lucia ; Leung, Nelson L C ; Xie, Ni ; Gu, Xinggui ; Sung, Herman H Y ; Miao, Qian ; Williams, Ian D ; Licandro, Emanuela ; Tang, Ben Zhong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-1ae052b76ec5ef9e73538fa95b489499659ecc6240838e30bb7f8573e54ba44c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Aggregates</topic><topic>Behavior</topic><topic>Crystals</topic><topic>Derivatives</topic><topic>Emission</topic><topic>Emission analysis</topic><topic>Luminescence</topic><topic>Photoluminescence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Viglianti, Lucia</creatorcontrib><creatorcontrib>Leung, Nelson L C</creatorcontrib><creatorcontrib>Xie, Ni</creatorcontrib><creatorcontrib>Gu, Xinggui</creatorcontrib><creatorcontrib>Sung, Herman H Y</creatorcontrib><creatorcontrib>Miao, Qian</creatorcontrib><creatorcontrib>Williams, Ian D</creatorcontrib><creatorcontrib>Licandro, Emanuela</creatorcontrib><creatorcontrib>Tang, Ben Zhong</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Viglianti, Lucia</au><au>Leung, Nelson L C</au><au>Xie, Ni</au><au>Gu, Xinggui</au><au>Sung, Herman H Y</au><au>Miao, Qian</au><au>Williams, Ian D</au><au>Licandro, Emanuela</au><au>Tang, Ben Zhong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aggregation-induced emission: mechanistic study of the clusteroluminescence of tetrathienylethene</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2017-04-01</date><risdate>2017</risdate><volume>8</volume><issue>4</issue><spage>2629</spage><epage>2639</epage><pages>2629-2639</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>In this work we have investigated the aggregation-induced emission (AIE) behaviour of 1,1,2,2-tetra(thiophen-2-yl)ethene (tetrathienylethene, TTE). 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)-1,2-di(thiophen-2-yl)ethene (
-dithienylethene, DTE). Crystal analysis has revealed that the emission red-shifts are ascribable to the presence of strong sulfur-sulfur (S···S) intra- and intermolecular interactions that are as close as 3.669 Å for TTE and 3.679 Å for DTE. These heteroatom interactions could help explain the photoluminescence of non-conventional luminophores as well as the luminescence of non-conjugated biomacromolecules.</abstract><cop>England</cop><pmid>28553498</pmid><doi>10.1039/c6sc05192h</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-9933-6548</orcidid><orcidid>https://orcid.org/0000-0001-8493-0886</orcidid><orcidid>https://orcid.org/0000-0002-0293-964X</orcidid><orcidid>https://orcid.org/0000-0002-3370-0332</orcidid><orcidid>https://orcid.org/0000-0003-3949-9622</orcidid><orcidid>https://orcid.org/0000-0003-0168-9295</orcidid><oa>free_for_read</oa></addata></record> |
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title | Aggregation-induced emission: mechanistic study of the clusteroluminescence of tetrathienylethene |
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