Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(ii) compounds

Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(ii) complexes of type [Co(C -terpy) ](C -Glu) (n = 15-20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (34), p.4685-4687
Main Authors: Akiyoshi, Ryohei, Kuroiwa, Keita, Alao Amolegbe, Saliu, Nakaya, Manabu, Ohtani, Ryo, Nakamura, Masaaki, Lindoy, Leonard F, Hayami, Shinya
Format: Article
Language:English
Subjects:
Alkylation
Architecture
Cationic
Chains
Crossovers
Magnetic permeability
Synthesis
Wire
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Summary:Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(ii) complexes of type [Co(C -terpy) ](C -Glu) (n = 15-20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(ii) centres exhibiting gradual spin-crossover behaviours.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc01501a