Removal of Erythrosine B dye from water effluents using crop waste pumpkin seed hulls as adsorbent

• Published in: Desalination and water treatment 2016-10, Vol.57 (47), p.22585-22608
• Main Authors: Carmen Apostol, Laura, Ghinea, Cristina, Alves, Madalena, Gavrilescu, Maria
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Adsorption mechanism; Agricultural wastes; Agrowaste; ANOVA; Carbonyl compounds; Carcinogenicity; Dyes; Food dye; Hulls; Hulls (structures); Kinetics; Organic wastes; Pore size; Pumpkin seed hul; Pumpkin seed hull; Pumpkins; Science & Technology; Seeds; Surface chemistry; Thermodynamics
• ISSN: 1944-3986; 1944-3994; 1944-3986
• DOI: 10.1080/19443994.2015.1132477

Erythrosine B is widely used for coloring in various applications, especially in the food industry, despite its already proved toxicity and carcinogenicity. The agrowaste pumpkin seed hulls were applied as potential adsorbent for the removal of Erythrosine from aqueous solutions. Adsorption mechanism and kinetics were analyzed for design purposes. The seed hulls were characterized by specific techniques before and after dye retention. It was found that the attachment of Erythrosine B molecules on adsorbent surface may be attributed to the interactions between carboxyl and/or carbonyl groups of both dye and agrowaste wall components. A univariate approach followed by a factorial design was applied to study and analyze the experimental results as well as to estimate the combined effects of the process factors on the removal efficiency and dye uptake. Adsorption mechanism may be predominantly due to intraparticle diffusion, dependent on pore size. The four equilibrium models applied fitted the data well; the maximum adsorption capacity for Erythrosine was 16.4 mg/g. The results showed that adsorbent is effective for Erythrosine B removal for a large concentration range in aqueous solutions (5–400 mg/L) in batch systems.