Progress in the research of radical anion ligands and their complexes

Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review. Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate radical, nitroxide radical, heterocycle radical etc. Structural characteristics and p...

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Bibliographic Details
Published in:Chinese science bulletin 2014-08, Vol.59 (24), p.2936-2944
Main Authors: Mao, Guoliang, Song, Yuanmeng, Hao, Tianjun, Li, Ying, Xu, Tao, Zhang, Haiyan, Jiang, Tao
Format: Article
Language:English
Subjects:
Anions
Catalysis
catalytic activity
Chemistry/Food Science
Coordination compounds
Earth Sciences
Engineering
Humanities and Social Sciences
Life Sciences
Ligands
Magnetic materials
metals
multidisciplinary
Physics
Radicals
Review
Science
Science (multidisciplinary)
Transition metals
复合物
有机磁性材料
杂环
氮氧自由基
过渡金属催化
配体
配合物
阴离子自由基
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Summary:Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review. Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate radical, nitroxide radical, heterocycle radical etc. Structural characteristics and properties of the corresponding complexes were introduced. The complexes exhibited novel properties and possibility for applications in organic magnetic materials and transition metal catalysis.
ISSN:1001-6538
1861-9541
DOI:10.1007/s11434-014-0326-2