Continuous Extraction of Nickel from Superalloy Scraps Using Zinc Circulation

• Published in: Metallurgical and materials transactions. B, Process metallurgy and materials processing science Process metallurgy and materials processing science, 2017-06, Vol.48 (3), p.1494-1501
• Main Authors: Yagi, Ryohei, Okabe, Toru H.
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Extraction; Materials Science; Metal scrap; Metallic Materials; Nanotechnology; Nickel; Nickel base alloys; Refractory metals; Structural Materials; Superalloys; Surfaces and Interfaces; Tantalum; Thin Films; Zinc
• ISSN: 1073-5615; 1543-1916
• DOI: 10.1007/s11663-017-0941-9

A novel technique for the continuous extraction of nickel (Ni) from Ni-based superalloy scraps using molten zinc (Zn) has been proposed, and its feasibility was experimentally demonstrated. The newly developed approach allows for extraction of Ni metal directly from superalloy scraps with simultaneous separation of the Zn from the resulting Zn-Ni alloy. The optimal conditions for the extraction of Ni and separation of valuable elements such as rhenium (Re), tantalum (Ta), and tungsten (W) were determined by varying major process parameters including the reaction time and configuration of the reaction chamber. The proposed method has been successfully utilized for the production of the superalloy containing 62.8 mass pct of Ni and 15.5 mass pct of refractory metals (Re, W, and Ta). Under certain conditions, 41 pct of the Ni contained in the superalloy could be extracted at 1173 K (900 °C) over 48 hours, producing an alloy containing 84.0 mass pct of Ni and 0.2 mass pct of the refractory metals.