Development of a linear-type double reflectron for focused imaging of photofragment ions from mass-selected complex ions

An ion imaging apparatus with a double linear reflectron mass spectrometer has been developed, in order to measure velocity and angular distributions of mass-analyzed fragment ions produced by photodissociation of mass-selected gas phase complex ions. The 1st and the 2nd linear reflectrons were plac...

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Bibliographic Details
Published in:Review of scientific instruments 2017-05, Vol.88 (5), p.053105-053105
Main Authors: Okutsu, Kenichi, Nakashima, Yuji, Yamazaki, Kenichiro, Fujimoto, Keita, Nakano, Motoyoshi, Ohshimo, Keijiro, Misaizu, Fuminori
Format: Article
Language:English
Subjects:
Angular velocity
Anisotropy
Calcium
Computer simulation
Electrodes
Finite element method
High voltages
Imaging
Ion trajectories
Photodissociation
Photoexcitation
Scientific apparatus & instruments
Voltage pulses
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Summary:An ion imaging apparatus with a double linear reflectron mass spectrometer has been developed, in order to measure velocity and angular distributions of mass-analyzed fragment ions produced by photodissociation of mass-selected gas phase complex ions. The 1st and the 2nd linear reflectrons were placed facing each other and controlled by high-voltage pulses in order to perform the mass-separation of precursor ions in the 1st reflectron and to observe the focused image of the photofragment ions in the 2nd reflectron. For this purpose, metal meshes were attached on all electrodes in the 1st reflectron, whereas the mesh was attached only on the last electrode in the 2nd reflectron. The performance of this apparatus was evaluated using imaging measurement of Ca+ photofragment ions from photodissociation reaction of Ca+Ar complex ions at 355 nm photoexcitation. The focused ion images were obtained experimentally with the double linear reflectron at the voltages of the reflection electrodes close to the predictions by ion trajectory simulations. The velocity and angular distributions of the produced Ca+ ([Ar] 4p1, 2P3/2) ion were analyzed from the observed images. The binding energy D 0 of Ca+Ar in the ground state deduced in the present measurement was consistent with those determined theoretically and by spectroscopic measurements. The anisotropy parameter β of the transition was evaluated for the first time by this instrument.
ISSN:0034-6748
1089-7623
DOI:10.1063/1.4982706