Loading…

An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units

Under solvothermal conditions, a chair open-framework borate, Na2B9O15(H2O)­(H3O) (1), has been synthesized. Compound 1 shows regular pores of zeolites as well as nonlinear optical (NLO) properties of borates. The large 13-ring channels of the boron oxide framework are constructed from different clu...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry 2017-06, Vol.56 (12), p.6780-6783
Main Authors: Wang, Er-Rong, Huang, Jian-Hao, Yu, Su-Juan, Lan, You-Zhao, Cheng, Jian-Wen, Yang, Guo-Yu
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Under solvothermal conditions, a chair open-framework borate, Na2B9O15(H2O)­(H3O) (1), has been synthesized. Compound 1 shows regular pores of zeolites as well as nonlinear optical (NLO) properties of borates. The large 13-ring channels of the boron oxide framework are constructed from different cluster units of B3O7 and B6O13 with three-ring units. The second harmonic generation (SHG) signal intensity of 1 is similar to that of KH2PO4 (KDP) and gradually increased with larger particle size. Compound 1 is a potential UV NLO material for its short wavelength absorption edge.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.7b00975