Effects of silane-modified fillers on properties of dental composite resin

• Published in: Materials Science & Engineering C 2017-10, Vol.79, p.382-389
• Main Authors: Aydinoglu, Aysu, Yoruç, Afife Binnaz Hazar
• Format: Article
• Language: English
• Subjects: 3-MPTMS; Bis-GMA resin; Bisphenol A-Glycidyl Methacrylate; Bonding agents; Chemical bonds; Composite Resins; Compressive strength; Curing; Degree of polymerization; Dental composite resin; Dental materials; Dental restorative materials; Effects; Fillers; Flexural strength; HEMA; Inorganic fillers; Ludox (trademark); Materials science; Materials Testing; Mechanical properties; Modulus of elasticity; Particle size; Physical properties; Polymer matrix composites; Polymerization; Polymethacrylic Acids; Polytetrafluoroethylene; Resins; Shrinkage; Silanes; Silanes - chemistry; Silica; Silicon Dioxide; Spectroscopy, Fourier Transform Infrared; Surface area; Surface Properties; Teeth; UDMA resin; X ray photoelectron spectroscopy
• ISSN: 0928-4931; 1873-0191
• DOI: 10.1016/j.msec.2017.04.151

The effect of silanization on the mechanical, chemical, and physical properties of dental composites was investigated. Silica fillers were obtained from colloidal silica solution, Ludox® HS-40 and they were silanized by using 3-methacryloxypropyl trimethoxysilane (MPTMS) in an acidic media. Mineralogical and chemical structures of unsilanized and silanized fillers were determined by using XRD and FT-IR analyses. The modification of unsilanized/silanized fillers were investigated by performing XPS and TGA analyses. The morphological evaluations, surface area, and particle size measurements were performed by using SEM, BET, and Zeta-Sizer, respectively. Eventually, pure and amorphous silica fillers were obtained. Furthermore, the weight percentage of the silane in silica/silane structure was compatible with theoretical values. SEM images, surface area, and particle size measurements showed that agglomeration tendencies of silanized fillers were lower compared to silanized fillers because of the MPTMS addition. Experimental composites (5/10/10/5BisGMA/HEMA/UDMA/TEGDMA resin reinforced with 70wt% silanized/unsilanized SiO2) were fabricated into 4mm diameter×6mm thick discs for compressive strength (CS), angular flexural strength (AFS), curing depth (CD), and polymerization shrinkage (PS) on a 25×2×2mm rectangular Teflon mold for flexural strength (FS) and modulus of elasticity (E) tests. The curing depth (CD) and degree of polymerization percentage (DP) of composites were determined. Consequently, results showed that mechanical properties and DP of composite resins can be greatly influenced by silanization as a result of the organic matrix-inorganic filler interface bonding formed by silane structures. Despite of these findings, silanization of the SiO2 was not effected DC and PS values. [Display omitted] •Silanization effect of inorganic fillers on polymerizable dental composites was investigated.•Compared to unsilanized fillers, dental composites with silanized fillers show better mechanical and chemical properties.•Physical features were not affected by the silanization of fillers.