Redox effects of low-spin Ru(ii/iii) on slow magnetic relaxation of Ru-Mn(iii) 1D cyanide-bridged complexes

A new one-dimensional cyanide-bridged complex [Mn (salphen)Ru (DMAP) (CN) ](PF ) (1) and its oxidized derivative [Mn (salphen)Ru (DMAP) (CN) ](PF ) (2) have been synthesized and fully characterized. Magnetic measurements showed that 1 shows simple paramagnetism but 2 shows intrachain ferromagnetic i...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2017-06, Vol.46 (22), p.7267-7272
Main Authors: Zhu, Xiaoquan, Su, Shaodong, Cao, Wenhai, Wen, Yuehong, Hu, Shengmin, Wu, Xintao, Sheng, Tianlu
Format: Article
Language:English
Subjects:
Derivatives
Ferromagnetism
Magnetic measurement
Magnetic relaxation
Paramagnetism
Synthesis
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Summary:A new one-dimensional cyanide-bridged complex [Mn (salphen)Ru (DMAP) (CN) ](PF ) (1) and its oxidized derivative [Mn (salphen)Ru (DMAP) (CN) ](PF ) (2) have been synthesized and fully characterized. Magnetic measurements showed that 1 shows simple paramagnetism but 2 shows intrachain ferromagnetic interaction with slow magnetic relaxation.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt01218g