New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex

A (μ-peroxo)diiron(iii) complex [Fe (L )(O )(Ph CCO )] (1-O ) with a dinucleating ligand (L ), generated from the reaction of a carboxylate bridged diiron(ii) complex [Fe (L )(Ph CCO )] (1) with dioxygen in CH Cl , provides a diiron(iv)-oxo species as an active oxidant which is involved in either ar...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017-08, Vol.53 (63), p.8838-8841
Main Authors: Sekino, Mio, Furutachi, Hideki, Tojo, Rina, Hishi, Ayumi, Kajikawa, Hanako, Suzuki, Takatoshi, Suzuki, Kaito, Fujinami, Shuhei, Akine, Shigehisa, Sakata, Yoko, Ohta, Takehiro, Hayami, Shinya, Suzuki, Masatatsu
Format: Article
Language:English
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Summary:A (μ-peroxo)diiron(iii) complex [Fe (L )(O )(Ph CCO )] (1-O ) with a dinucleating ligand (L ), generated from the reaction of a carboxylate bridged diiron(ii) complex [Fe (L )(Ph CCO )] (1) with dioxygen in CH Cl , provides a diiron(iv)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc04382a