High molecular weight poly(N-methyl-B-vinylazaborine) - a semi-inorganic B-N polystyrene analogue

We present the synthesis of a B-N analogue of polystyrene, poly(N-methyl-B-vinylazaborine) in high molecular weight (M = 24.9 kDa). Furthermore, it was possible to prepare a copolymer with the C-C analogue. A thorough comparison between the polymers by NMR spectroscopy, TGA, DSC and GPC showed signi...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017-06, Vol.53 (53), p.7258-7261
Main Authors: Thiedemann, Birk, Gliese, Philipp J, Hoffmann, Jonas, Lawrence, Paul G, Sönnichsen, Frank D, Staubitz, Anne
Format: Article
Language:English
Subjects:
Analogue
Carbon-carbon composites
Copolymers
Molecular weight
NMR spectroscopy
Polystyrene resins
Synthesis (chemistry)
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Summary:We present the synthesis of a B-N analogue of polystyrene, poly(N-methyl-B-vinylazaborine) in high molecular weight (M = 24.9 kDa). Furthermore, it was possible to prepare a copolymer with the C-C analogue. A thorough comparison between the polymers by NMR spectroscopy, TGA, DSC and GPC showed significant differences between these polymers.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc08599g