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Metal free mild and selective aldehyde cyanosilylation by a neutral penta-coordinate silicon compound

This study demonstrates the preparation and structural characterization of a Si(iv) hydride (PhC(NtBu) SiH(CH )Cl) (1) and its use as a catalyst for the cyanosilylation of a variety of aldehydes. Compound 1 represents the first neutral penta-coordinate silicon(iv) species that catalyzes cyanosilylat...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (51), p.6910-6913
Main Authors: Swamy, V S V S N, Bisai, Milan Kumar, Das, Tamal, Sen, Sakya S
Format: Article
Language:English
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Summary:This study demonstrates the preparation and structural characterization of a Si(iv) hydride (PhC(NtBu) SiH(CH )Cl) (1) and its use as a catalyst for the cyanosilylation of a variety of aldehydes. Compound 1 represents the first neutral penta-coordinate silicon(iv) species that catalyzes cyanosilylation of aldehydes under mild conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc03948d