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Metal free mild and selective aldehyde cyanosilylation by a neutral penta-coordinate silicon compound
This study demonstrates the preparation and structural characterization of a Si(iv) hydride (PhC(NtBu) SiH(CH )Cl) (1) and its use as a catalyst for the cyanosilylation of a variety of aldehydes. Compound 1 represents the first neutral penta-coordinate silicon(iv) species that catalyzes cyanosilylat...
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Published in: | Chemical communications (Cambridge, England) England), 2017, Vol.53 (51), p.6910-6913 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | This study demonstrates the preparation and structural characterization of a Si(iv) hydride (PhC(NtBu)
SiH(CH
)Cl) (1) and its use as a catalyst for the cyanosilylation of a variety of aldehydes. Compound 1 represents the first neutral penta-coordinate silicon(iv) species that catalyzes cyanosilylation of aldehydes under mild conditions. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c7cc03948d |