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Trace element concentrations in the groundwater of the Tamiraparani river basin, South India: Insights from human health risk and multivariate statistical techniques

This study investigates the concentration of trace elements in the groundwater of Tamiraparani river basin, South India. 124 groundwater samples were collected representing diverse landuse condition over the study area. The results reveal that the mean concentrations of Fe, Mn, Cu, Cr, Pb, Zn and Ni...

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Bibliographic Details
Published in:Chemosphere (Oxford) 2017-10, Vol.185, p.468-479
Main Authors: Magesh, N.S., Chandrasekar, N., Elango, L.
Format: Article
Language:English
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Summary:This study investigates the concentration of trace elements in the groundwater of Tamiraparani river basin, South India. 124 groundwater samples were collected representing diverse landuse condition over the study area. The results reveal that the mean concentrations of Fe, Mn, Cu, Cr, Pb, Zn and Ni were 0.269, 0.02, 0.007, 0.007, 0.003, 0.066, and 0.004 ppm respectively. The decreasing trend of trace element content shows the following order: Fe > Zn > Mn > Cu > Cr > Ni > Pb. Significant positive correlation (p  Zn > Mn > Cu > Cr > Ni > Pb and Fe > Zn > Mn > Cr > Cu > Ni > Pb respectively. The Hazard quotients suggest that the risk of contamination through oral and dermal pathways is feeble as all the elements show values less than one. The multivariate statistical analysis reveals that the source of trace elements in the groundwater is through natural origin except copper, chromium and lead as these contaminants are derived from anthropogenic activities. •Trace elements in the groundwater of Tamiraparani river basin is modeled spatially.•Elemental concentrations were compared with WHO standards.•Emprical bayesian kriging was used and prediction errors were quantified.•Health risk assessment was done through oral and dermal pathways.•Multivariate statistical analysis were used to infer the source.
ISSN:0045-6535
1879-1298
DOI:10.1016/j.chemosphere.2017.07.044