Aqueous Exfoliation of Graphite into Graphene Assisted by Sulfonyl Graphene Quantum Dots for Photonic Crystal Applications

We investigate the π–π stacking of polyaromatic hydrocarbons (PAHs) with graphene surfaces, showing that such interactions are general across a wide range of PAH sizes and species, including graphene quantum dots. We synthesized a series of graphene quantum dots with sulfonyl, amino, and carboxylic...

Full description

Saved in:
Bibliographic Details
Published in:ACS applied materials & interfaces 2017-09, Vol.9 (36), p.30797-30804
Main Authors: Zeng, Minxiang, Shah, Smit A, Huang, Dali, Parviz, Dorsa, Yu, Yi-Hsien, Wang, Xuezhen, Green, Micah J, Cheng, Zhengdong
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a330t-cb58a1314230a9f3b1a7e16f2592d8df084d93428fae6d5c9e7b415bf49b6d0c3
cites cdi_FETCH-LOGICAL-a330t-cb58a1314230a9f3b1a7e16f2592d8df084d93428fae6d5c9e7b415bf49b6d0c3
container_end_page 30804
container_issue 36
container_start_page 30797
container_title ACS applied materials & interfaces
container_volume 9
creator Zeng, Minxiang
Shah, Smit A
Huang, Dali
Parviz, Dorsa
Yu, Yi-Hsien
Wang, Xuezhen
Green, Micah J
Cheng, Zhengdong
description We investigate the π–π stacking of polyaromatic hydrocarbons (PAHs) with graphene surfaces, showing that such interactions are general across a wide range of PAH sizes and species, including graphene quantum dots. We synthesized a series of graphene quantum dots with sulfonyl, amino, and carboxylic functional groups and employed them to exfoliate and disperse pristine graphene in water. We observed that sulfonyl-functionalized graphene quantum dots were able to stabilize the highest concentration of graphene in comparison to other functional groups; this is consistent with prior findings by pyrene. The graphene nanosheets prepared showed excellent colloidal stability, indicating great potential for applications in electronics, solar cells, and photonic displays which was demonstrated in this work.
doi_str_mv 10.1021/acsami.7b06980
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1930481182</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1930481182</sourcerecordid><originalsourceid>FETCH-LOGICAL-a330t-cb58a1314230a9f3b1a7e16f2592d8df084d93428fae6d5c9e7b415bf49b6d0c3</originalsourceid><addsrcrecordid>eNp1kM9LwzAUx4Mobk6vHiVHETrzq116HHNOYaCinkPaJiyjbWqSgvWvt7Nznjy993if9318vwBcYjTFiOBbmXtZmeksQ0nK0REY45SxiJOYHB96xkbgzPstQgklKD4FI8I5ThjhY_A1_2iVbT1cfmpbGhmMraHVcOVkszFBQVMHO0yqVnDuvfFBFTDr4Gtbalt35d_2pZV1aCt4Z4OH2jr4vLHB1iaHC9f5IEs4b5rS5D9f_Dk40bL06mJfJ-D9fvm2eIjWT6vHxXwdSUpRiPIs5hJTzAhFMtU0w3KmcKJJnJKCFxpxVqS0N6OlSoo4T9UsYzjONEuzpEA5nYDrQbdxtjfrg6iMz1VZynrnXOCUIsYx5qRHpwOaO-u9U1o0zlTSdQIjsctbDHmLfd79wdVeu80qVRzw34B74GYA-kOxta2re6v_qX0DbeKMzA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1930481182</pqid></control><display><type>article</type><title>Aqueous Exfoliation of Graphite into Graphene Assisted by Sulfonyl Graphene Quantum Dots for Photonic Crystal Applications</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Zeng, Minxiang ; Shah, Smit A ; Huang, Dali ; Parviz, Dorsa ; Yu, Yi-Hsien ; Wang, Xuezhen ; Green, Micah J ; Cheng, Zhengdong</creator><creatorcontrib>Zeng, Minxiang ; Shah, Smit A ; Huang, Dali ; Parviz, Dorsa ; Yu, Yi-Hsien ; Wang, Xuezhen ; Green, Micah J ; Cheng, Zhengdong</creatorcontrib><description>We investigate the π–π stacking of polyaromatic hydrocarbons (PAHs) with graphene surfaces, showing that such interactions are general across a wide range of PAH sizes and species, including graphene quantum dots. We synthesized a series of graphene quantum dots with sulfonyl, amino, and carboxylic functional groups and employed them to exfoliate and disperse pristine graphene in water. We observed that sulfonyl-functionalized graphene quantum dots were able to stabilize the highest concentration of graphene in comparison to other functional groups; this is consistent with prior findings by pyrene. The graphene nanosheets prepared showed excellent colloidal stability, indicating great potential for applications in electronics, solar cells, and photonic displays which was demonstrated in this work.</description><identifier>ISSN: 1944-8244</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.7b06980</identifier><identifier>PMID: 28816428</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>ACS applied materials &amp; interfaces, 2017-09, Vol.9 (36), p.30797-30804</ispartof><rights>Copyright © 2017 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a330t-cb58a1314230a9f3b1a7e16f2592d8df084d93428fae6d5c9e7b415bf49b6d0c3</citedby><cites>FETCH-LOGICAL-a330t-cb58a1314230a9f3b1a7e16f2592d8df084d93428fae6d5c9e7b415bf49b6d0c3</cites><orcidid>0000-0003-0929-4749 ; 0000-0001-5691-0861</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28816428$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zeng, Minxiang</creatorcontrib><creatorcontrib>Shah, Smit A</creatorcontrib><creatorcontrib>Huang, Dali</creatorcontrib><creatorcontrib>Parviz, Dorsa</creatorcontrib><creatorcontrib>Yu, Yi-Hsien</creatorcontrib><creatorcontrib>Wang, Xuezhen</creatorcontrib><creatorcontrib>Green, Micah J</creatorcontrib><creatorcontrib>Cheng, Zhengdong</creatorcontrib><title>Aqueous Exfoliation of Graphite into Graphene Assisted by Sulfonyl Graphene Quantum Dots for Photonic Crystal Applications</title><title>ACS applied materials &amp; interfaces</title><addtitle>ACS Appl. Mater. Interfaces</addtitle><description>We investigate the π–π stacking of polyaromatic hydrocarbons (PAHs) with graphene surfaces, showing that such interactions are general across a wide range of PAH sizes and species, including graphene quantum dots. We synthesized a series of graphene quantum dots with sulfonyl, amino, and carboxylic functional groups and employed them to exfoliate and disperse pristine graphene in water. We observed that sulfonyl-functionalized graphene quantum dots were able to stabilize the highest concentration of graphene in comparison to other functional groups; this is consistent with prior findings by pyrene. The graphene nanosheets prepared showed excellent colloidal stability, indicating great potential for applications in electronics, solar cells, and photonic displays which was demonstrated in this work.</description><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kM9LwzAUx4Mobk6vHiVHETrzq116HHNOYaCinkPaJiyjbWqSgvWvt7Nznjy993if9318vwBcYjTFiOBbmXtZmeksQ0nK0REY45SxiJOYHB96xkbgzPstQgklKD4FI8I5ThjhY_A1_2iVbT1cfmpbGhmMraHVcOVkszFBQVMHO0yqVnDuvfFBFTDr4Gtbalt35d_2pZV1aCt4Z4OH2jr4vLHB1iaHC9f5IEs4b5rS5D9f_Dk40bL06mJfJ-D9fvm2eIjWT6vHxXwdSUpRiPIs5hJTzAhFMtU0w3KmcKJJnJKCFxpxVqS0N6OlSoo4T9UsYzjONEuzpEA5nYDrQbdxtjfrg6iMz1VZynrnXOCUIsYx5qRHpwOaO-u9U1o0zlTSdQIjsctbDHmLfd79wdVeu80qVRzw34B74GYA-kOxta2re6v_qX0DbeKMzA</recordid><startdate>20170913</startdate><enddate>20170913</enddate><creator>Zeng, Minxiang</creator><creator>Shah, Smit A</creator><creator>Huang, Dali</creator><creator>Parviz, Dorsa</creator><creator>Yu, Yi-Hsien</creator><creator>Wang, Xuezhen</creator><creator>Green, Micah J</creator><creator>Cheng, Zhengdong</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0929-4749</orcidid><orcidid>https://orcid.org/0000-0001-5691-0861</orcidid></search><sort><creationdate>20170913</creationdate><title>Aqueous Exfoliation of Graphite into Graphene Assisted by Sulfonyl Graphene Quantum Dots for Photonic Crystal Applications</title><author>Zeng, Minxiang ; Shah, Smit A ; Huang, Dali ; Parviz, Dorsa ; Yu, Yi-Hsien ; Wang, Xuezhen ; Green, Micah J ; Cheng, Zhengdong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a330t-cb58a1314230a9f3b1a7e16f2592d8df084d93428fae6d5c9e7b415bf49b6d0c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zeng, Minxiang</creatorcontrib><creatorcontrib>Shah, Smit A</creatorcontrib><creatorcontrib>Huang, Dali</creatorcontrib><creatorcontrib>Parviz, Dorsa</creatorcontrib><creatorcontrib>Yu, Yi-Hsien</creatorcontrib><creatorcontrib>Wang, Xuezhen</creatorcontrib><creatorcontrib>Green, Micah J</creatorcontrib><creatorcontrib>Cheng, Zhengdong</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ACS applied materials &amp; interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zeng, Minxiang</au><au>Shah, Smit A</au><au>Huang, Dali</au><au>Parviz, Dorsa</au><au>Yu, Yi-Hsien</au><au>Wang, Xuezhen</au><au>Green, Micah J</au><au>Cheng, Zhengdong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aqueous Exfoliation of Graphite into Graphene Assisted by Sulfonyl Graphene Quantum Dots for Photonic Crystal Applications</atitle><jtitle>ACS applied materials &amp; interfaces</jtitle><addtitle>ACS Appl. Mater. Interfaces</addtitle><date>2017-09-13</date><risdate>2017</risdate><volume>9</volume><issue>36</issue><spage>30797</spage><epage>30804</epage><pages>30797-30804</pages><issn>1944-8244</issn><eissn>1944-8252</eissn><abstract>We investigate the π–π stacking of polyaromatic hydrocarbons (PAHs) with graphene surfaces, showing that such interactions are general across a wide range of PAH sizes and species, including graphene quantum dots. We synthesized a series of graphene quantum dots with sulfonyl, amino, and carboxylic functional groups and employed them to exfoliate and disperse pristine graphene in water. We observed that sulfonyl-functionalized graphene quantum dots were able to stabilize the highest concentration of graphene in comparison to other functional groups; this is consistent with prior findings by pyrene. The graphene nanosheets prepared showed excellent colloidal stability, indicating great potential for applications in electronics, solar cells, and photonic displays which was demonstrated in this work.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>28816428</pmid><doi>10.1021/acsami.7b06980</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-0929-4749</orcidid><orcidid>https://orcid.org/0000-0001-5691-0861</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1944-8244
ispartof ACS applied materials & interfaces, 2017-09, Vol.9 (36), p.30797-30804
issn 1944-8244
1944-8252
language eng
recordid cdi_proquest_miscellaneous_1930481182
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
title Aqueous Exfoliation of Graphite into Graphene Assisted by Sulfonyl Graphene Quantum Dots for Photonic Crystal Applications
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T23%3A16%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Aqueous%20Exfoliation%20of%20Graphite%20into%20Graphene%20Assisted%20by%20Sulfonyl%20Graphene%20Quantum%20Dots%20for%20Photonic%20Crystal%20Applications&rft.jtitle=ACS%20applied%20materials%20&%20interfaces&rft.au=Zeng,%20Minxiang&rft.date=2017-09-13&rft.volume=9&rft.issue=36&rft.spage=30797&rft.epage=30804&rft.pages=30797-30804&rft.issn=1944-8244&rft.eissn=1944-8252&rft_id=info:doi/10.1021/acsami.7b06980&rft_dat=%3Cproquest_cross%3E1930481182%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a330t-cb58a1314230a9f3b1a7e16f2592d8df084d93428fae6d5c9e7b415bf49b6d0c3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1930481182&rft_id=info:pmid/28816428&rfr_iscdi=true