Magnetic diversity in three-dimensional two-fold-interpenetrated structures: a story of two compounds

• Published in: Dalton transactions : an international journal of inorganic chemistry 2017-10, Vol.46 (38), p.12804-12810
• Main Authors: Rao, Purna Chandra, Chaudhary, Sonu Pratap, Arjun, U, Kuznetsov, Denis, Nath, Ramesh Chandra, Mandal, Sukhendu
• Format: Article
• Language: English
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/c7dt02004j

A magnetostructural correlation has been carried out for two newly synthesized two-fold-interpenetrated three-dimensional structures. Compound 1, denoted as [Ni(L1)(L2)]·2DMF (where L1 is 1,4-benzene-dicarboxylic acid (BDC), L2 is 4,4-oxybis-(N-(pyridine-4-yl)benzamide), and DMF is N,N'-dimethylformamide), was observed to have a three-dimensional structure with two-fold interpenetration. Compound 2, denoted as [Co(L3)(L2)]·2DMF (where L3 is 2,5-thiopehene-dicarboxylic acid (TDC)), was also observed to display a three-dimensional structure with an architecture identical to that of compound 1. Both compounds were well characterised using several techniques including single-crystal X-ray diffraction, powder X-ray diffraction, TGA, and IR. Magnetism and specific heat measurements of compound 1 revealed a canted-antiferromagnetic transition at T ≈ 4 K and a field-induced spin-flop transition at a relatively low field strength. These exotic features were attributed to the low-symmetry space group P(1[combining macron]) and single-ion anisotropy of the Ni sub-lattice. In contrast, compound 2 was found to be weakly antiferromagnetic in nature with a negligible interaction between the magnetic Co ions.