Polylactide/graphene oxide nanosheets/clove essential oil composite films for potential food packaging applications

•Polylactide was duped with clove essential oil and graphene oxide nanosheets.•Graphene oxide loading improved thermo-mechanical and barrier properties.•Clove oil improved the flexibility of the composite films.•PLA/GO/CLO composite film could be used as an antimicrobial packaging material. Antimicr...

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Bibliographic Details
Published in:International journal of biological macromolecules 2018-02, Vol.107 (Pt A), p.194-203
Main Authors: Arfat, Yasir Ali, Ahmed, Jasim, Ejaz, Mohammed, Mullah, Mehrajfatimah
Format: Article
Language:English
Subjects:
Clove oil
Clove Oil - chemistry
Food Packaging
Glass transition temperature
Graphene oxide nanosheets
Graphite - chemistry
Nanocomposite
Nanocomposites - chemistry
Nanostructures - chemistry
Oils, Volatile - chemistry
Polyesters - chemistry
Polylactide
Rheology
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Summary:•Polylactide was duped with clove essential oil and graphene oxide nanosheets.•Graphene oxide loading improved thermo-mechanical and barrier properties.•Clove oil improved the flexibility of the composite films.•PLA/GO/CLO composite film could be used as an antimicrobial packaging material. Antimicrobial nanopackaging films were developed by incorporating clove essential oil (CLO) (15–30% w/w) and graphene oxide (GO) nanosheets (1% w/w) into polylactide (PLA), suitable for use as food packaging, via solution casting. Addition of CLO into PLA matrix improved the flexibility of the composite films by lowering tensile stress, complex viscosity (η*), and glass transition temperature (Tg). GO improved the Tg, η* and lowered the oxygen permeability of the plasticized PLA matrix. Optical and anti-UV properties of the film were influenced by both GO and CLO incorporation. FTIR spectra exhibited a change in the molecular organization of the plasticized PLA film after incorporation with CLO. Microstructural studies revealed that the reinforcement of GO prevented porosity of plasticized PLA/CLO film surface. The developed composite film showed excellent antibacterial activity against Staphylococcus aureus and Escherichia coli and therefore, has a potential to be used as active packaging material for food safety and preservation.
ISSN:0141-8130
1879-0003
DOI:10.1016/j.ijbiomac.2017.08.156