Achieving the interfacial polarization on C/Fe3C heterojunction structures for highly efficient lightweight microwave absorption

• Published in: Journal of colloid and interface science 2017-12, Vol.508, p.462-468
• Main Authors: Zhang, Yanan, Liu, Wei, Quan, Bin, Ji, Guangbin, Ma, Jianna, Li, Daoran, Meng, Wei
• Format: Article
• Language: English
• Subjects: C/Fe3C composites; Heterostructure; Honeycomb-like; Interface; Light-weight
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2017.08.074

Porous C/Fe3C heterojunctions with effective interfacial polarization have been fabricated by a facile strategy. By changing the addition of Fe(NO3)3·9H2O, its morphology and EM absorption could be regulated. [Display omitted] Design of dielectric/magnetic heterostructure and multiple interfaces is a challenge for the microwave absorption. Thus, in this study, a novel C/Fe3C nanocomposites have been fabricated by annealing the precursors obtained by the facile chemical blowing of polyvinyl pyrrolidone (PVP) and Fe(NO3)3·9H2O. By changing the content of Fe(NO3)3·9H2O, the honeycomb-like structure with scads of pores and electromagnetic parameters could be successfully tailored. When the addition of Fe(NO3)3·9H2O is ranging from 1 to 2g, honeycomb-structured nanocomposites possess high performance microwave absorption when mixed with 90wt% paraffin. The minimal reflection loss is −37.4dB at 13.6GHz and effective bandwidth can reach to 5.6GHz when the thickness is 2.0mm, indicating its great potential in microwave absorbing field. Its outstanding microwave performance is tightly related to the porous structure and substantial interface such as carbon/air and carbon/Fe3C, which are in favor of the impedance matching and interfacial polarization. Thus, our study may provide a good reference for the facile synthesis of light-weight carbon-based nanocomposites with effective interfacial polarization.