Influence of Ionic Strength on the Deposition of Metal–Phenolic Networks

Metal–phenolic networks (MPNs) are a versatile class of self-assembled materials that are able to form functional thin films on various substrates with potential applications in areas including drug delivery and catalysis. Different metal ions (e.g., FeIII, CuII) and phenols (e.g., tannic acid, gall...

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Bibliographic Details
Published in:Langmuir 2017-10, Vol.33 (40), p.10616-10622
Main Authors: Guo, Junling, Richardson, Joseph J, Besford, Quinn A, Christofferson, Andrew J, Dai, Yunlu, Ong, Chien W, Tardy, Blaise L, Liang, Kang, Choi, Gwan H, Cui, Jiwei, Yoo, Pil J, Yarovsky, Irene, Caruso, Frank
Format: Article
Language:English
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Summary:Metal–phenolic networks (MPNs) are a versatile class of self-assembled materials that are able to form functional thin films on various substrates with potential applications in areas including drug delivery and catalysis. Different metal ions (e.g., FeIII, CuII) and phenols (e.g., tannic acid, gallic acid) have been investigated for MPN film assembly; however, a mechanistic understanding of the thermodynamics governing MPN formation remains largely unexplored. To date, MPNs have been deposited at low ionic strengths (
ISSN:0743-7463
1520-5827
DOI:10.1021/acs.langmuir.7b02692