A new Mo(iv) complex with the pentadentate (N 3 O 2 ) Schiff-base ligand: the first non-cyanide pentagonal-bipyramidal paramagnetic 4d complex

A heptacoordinate complex [Mo (DAPBH)Cl ] (H DAPBH is 1,1'-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene)dibenzohydrazine) has been synthesized and characterized structurally and magnetically. It exhibits a slightly distorted pentagonal bipyramidal geometry and reveals paramagnetic behaviour resu...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2017-10, Vol.46 (41), p.14083-14087
Main Authors: Mironov, V S, Bazhenova, T A, Manakin, Yu V, Lyssenko, K A, Talantsev, A D, Yagubskii, E B
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cited_by cdi_FETCH-LOGICAL-c287t-1f2c7de1efea22971ace118b8a348a679521bf7a947723ef61973dc0b806b5093
cites cdi_FETCH-LOGICAL-c287t-1f2c7de1efea22971ace118b8a348a679521bf7a947723ef61973dc0b806b5093
container_end_page 14087
container_issue 41
container_start_page 14083
container_title Dalton transactions : an international journal of inorganic chemistry
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creator Mironov, V S
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Lyssenko, K A
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description A heptacoordinate complex [Mo (DAPBH)Cl ] (H DAPBH is 1,1'-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene)dibenzohydrazine) has been synthesized and characterized structurally and magnetically. It exhibits a slightly distorted pentagonal bipyramidal geometry and reveals paramagnetic behaviour resulting from two unpaired electrons (S = 1) with large positive zero-field splitting (D = +50 cm ) and pronounced temperature-independent paramagnetism.
doi_str_mv 10.1039/c7dt02912h
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title A new Mo(iv) complex with the pentadentate (N 3 O 2 ) Schiff-base ligand: the first non-cyanide pentagonal-bipyramidal paramagnetic 4d complex
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