The active site for the water oxidising anodic iridium oxide probed through in situ Raman spectroscopy

The structure of anodic iridium oxide (IrO ) under water oxidation was explored using in situ Raman spectroscopy and theoretical calculations. Isotopic substitution experiments and theoretical calculations confirmed formation of an Ir[double bond, length as m-dash]O species during oxygen evolution r...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (92), p.12414-12417
Main Authors: Pavlovic, Zoran, Ranjan, Chinmoy, van Gastel, Maurice, Schlögl, Robert
Format: Article
Language:English
Subjects:
Anodizing
Iridium
Mathematical analysis
Oxidation
Oxygen evolution reactions
Raman spectroscopy
Spectrum analysis
Substitution reactions
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Summary:The structure of anodic iridium oxide (IrO ) under water oxidation was explored using in situ Raman spectroscopy and theoretical calculations. Isotopic substitution experiments and theoretical calculations confirmed formation of an Ir[double bond, length as m-dash]O species during oxygen evolution reaction.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc05669a