Li+‑Permeable Film on Lithium Anode for Lithium Sulfur Battery

Lithium–sulfur (Li–S) battery is an important candidate for next-generation energy storage. However, the reaction between polysulfide and lithium (Li) anode brings poor cycling stability, low Coulombic efficiency, and Li corrosion. Herein, we report a Li protection technology. Li metal was treated i...

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Published in:ACS applied materials & interfaces 2017-11, Vol.9 (44), p.38950-38958
Main Authors: Yang, Yan-bo, Liu, Yun-xia, Song, Zhiping, Zhou, Yun-hong, Zhan, Hui
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Language:English
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container_issue 44
container_start_page 38950
container_title ACS applied materials & interfaces
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creator Yang, Yan-bo
Liu, Yun-xia
Song, Zhiping
Zhou, Yun-hong
Zhan, Hui
description Lithium–sulfur (Li–S) battery is an important candidate for next-generation energy storage. However, the reaction between polysulfide and lithium (Li) anode brings poor cycling stability, low Coulombic efficiency, and Li corrosion. Herein, we report a Li protection technology. Li metal was treated in crown ether containing electrolyte, and thus, treated Li was further used as the anode in Li–S cell. Due to the coordination between Li+ and crown ether, a Li+-permeable film can be formed on Li, and the film is proved to be able to block the detrimental reaction between Li anode and polysulfide. By using the Li anode pretreated in 2 wt % B15C5-containing electrolyte, Li–S cell exhibits significantly improved cycling stability, such as∼900 mAh g–1 after 100 cycles, and high Coulombic efficiency of>93%. In addition, such effect is also notable when high S loading condition is applied.
doi_str_mv 10.1021/acsami.7b10306
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title Li+‑Permeable Film on Lithium Anode for Lithium Sulfur Battery
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