Fabrication of water-dispersible single-walled carbon nanotube powder using N-methylmorpholine N-oxide

• Published in: Nanotechnology 2017-11, Vol.28 (46), p.465706-465706
• Main Authors: Choi, Hyejun, Seok Woo, Jong, Tark Han, Joong, Park, Soo-Young
• Format: Article
• Language: English
• Subjects: dispersion; flexible conductor; N-methylmorpholine N-oxide monohydrate; single-walled carbon nanotubes
• ISSN: 0957-4484; 1361-6528
• DOI: 10.1088/1361-6528/aa8c24

Dispersion of nanocarbon materials in liquid media, via solution processing such as spraying, printing, spinning, etc. is one of the prerequisites for practical applications. Here we report that water-dispersible single-walled carbon nanotubes (SWCNTs) were prepared through successive treatments with chlorosulfuric acid (CSA)/H2O2 and N-methylmorpholine N-oxide (NMO) monohydrate. The powder of the CSA/H2O2- and NMO-treated SWCNTs (N-SWCNTs) could be readily redispersed in water in concentrations as high as 1 g l−1 without requiring a dispersant. The mechanism responsible for the high dispersity of the N-SWCNT powder in polar solvents, including water, was elucidated based on the high polarity of the NMO molecule. In order to highlight the wide applicability of the N-SWCNTs, they were used successfully to prepare conducting thin films by spray-coating plastic substrates with an aqueous hybrid solution containing the N-SWCNTs and Ag nanowires (NWs). In addition, a flexible, large-area thin-film heater was prepared based on the N-SWCNT/AgNW hybrid film with a transmittance of 93% and sheet resistance of 30 sq−1.