Antimony mobility in Japanese agricultural soils and the factors affecting antimony sorption behavior

• Published in: Environmental pollution (1987) 2006-05, Vol.141 (2), p.321-326
• Main Authors: Nakamaru, Yasuo, Tagami, Keiko, Uchida, Shigeo
• Format: Article
• Language: English
• Subjects: Adsorption; agricultural soils; Agriculture; Antimony; Antimony - chemistry; Applied sciences; Biological and physicochemical properties of pollutants. Interaction in the soil; Distribution coefficient; Earth sciences; Earth, ocean, space; Engineering and environment geology. Geothermics; Environmental Monitoring - methods; Exact sciences and technology; Hydrogen-Ion Concentration; Ion Exchange; Japan; Mobility; nitrates; Nitrates - analysis; phosphates; Phosphates - analysis; polluted soils; Pollution; Pollution, environment geology; Radioisotopes - analysis; Soil; Soil - analysis; Soil and sediments pollution; soil pH; Soil Pollutants - analysis; soil pollution; Soil solution; sorption; Sorption behavior
• ISSN: 0269-7491; 1873-6424
• DOI: 10.1016/j.envpol.2005.08.040

The mobility of antimony (Sb) in Japanese agricultural soils was studied by radiotracer experiments using 124Sb tracer. The soil–solution distribution coefficients ( K d) of Sb were measured for 110 soil samples. These K ds ranged from 1 to 2065 L kg −1; the geometric mean was 62 L kg −1 excluding one extremely high value, 2065 L kg −1. Experimental measurement of K d showed a decrease with both increasing pH and increasing phosphate concentration. The latter suggested that one aspect of the Sb sorption phenomena in Japanese soil was influenced by specific adsorption of anions such as phosphate. However, other aspects could not be explained by this specific adsorption mechanism, because only 20–40% of soil-sorbed Sb could be extracted by phosphate solution. Antimony mobility in tested Japanese agricultural soils was generally low and was affected by pH and phosphate concentration.