A general method of Suzuki-Miyaura cross-coupling of 4- and 5-halo-1,2,3-triazoles in water

A general method of the synthesis of 1,4,5-trisubstituted-1,2,3-triazoles by Suzuki-Miyaura cross-coupling from 4- and 5-halo-1,2,3-triazoles is reported. The reaction is mediated by an expanded-ring N-heterocyclic carbene palladium complex in water. The developed reaction protocol meets the require...

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Published in:Organic & biomolecular chemistry 2017-11, Vol.15 (45), p.9575-9578
Main Authors: Gribanov, Pavel S, Chesnokov, Gleb A, Topchiy, Maxim A, Asachenko, Andrey F, Nechaev, Mikhail S
Format: Article
Language:English
Subjects:
Coupling
Cross coupling
Green chemistry
Green development
Palladium
Triazoles
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cited_by cdi_FETCH-LOGICAL-c337t-b7229bd088f199c517619490e59a20edfdfad095bc89e3f37320466a82f4fd083
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container_issue 45
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creator Gribanov, Pavel S
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description A general method of the synthesis of 1,4,5-trisubstituted-1,2,3-triazoles by Suzuki-Miyaura cross-coupling from 4- and 5-halo-1,2,3-triazoles is reported. The reaction is mediated by an expanded-ring N-heterocyclic carbene palladium complex in water. The developed reaction protocol meets the requirements of "green chemistry". Cross-coupling of 4- and 5-chlorotriazoles is reported for the first time. A general method of the synthesis of 1,4,5-trisubstituted-1,2,3-triazoles by Suzuki-Miyaura cross-coupling from 4- and 5-halo-1,2,3-triazoles.
doi_str_mv 10.1039/c7ob02091k
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source Royal Society of Chemistry
subjects Coupling
Cross coupling
Green chemistry
Green development
Palladium
Triazoles
title A general method of Suzuki-Miyaura cross-coupling of 4- and 5-halo-1,2,3-triazoles in water
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