Studies on thermal decomposition mechanism of CL-20 by pyrolysis gas chromatography–mass spectrometry (Py-GC/MS)

• Published in: Journal of hazardous materials 2008-11, Vol.159 (2), p.630-635
• Main Authors: Naik, N.H., Gore, G.M., Gandhe, B.R., Sikder, A.K.
• Format: Article
• Language: English
• Subjects: 1,4-Dinitro piperazine; Applied sciences; Bridged-Ring Compounds - chemistry; Chromatography, High Pressure Liquid; Chromatography, Ion Exchange; CL-20; Decomposition mechanism; Exact sciences and technology; Gas Chromatography-Mass Spectrometry; Hot Temperature; Mass Spectrometry; Nitro Compounds - chemistry; Nitrosamines - chemistry; Pollution; Pyrolysis GC/MS; Tetraacetylhexaazaisowurtzitane
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2008.02.049

The thermal decomposition study of CL-20 (hexanitrohexaazaisowurtzitane) using pyrolysis GC/MS was carried out mainly by electron impact (EI) mode. Chemical ionization (CI) mode was used for further confirmation of identified species. Mass spectrum of CL-20 decomposition products predominantly revealed fragments with m/ z 81 and 96 corresponding to C 4H 5N 2 + and C 4H 4N 2O + ions, respectively. The total ion chromatogram (TIC) of CL-20 pyrolysis shows peak within first 2 min due to the presence of low molecular weight gases. Peaks corresponding to several other products were also observed including the atmospheric gases. Cyanogen formation (C 2N 2, m/ z 52) observed to be enriched at the scan number 300–500. The low molecular mass range decomposition products formed by cleavage of C–N ring structure were found in majority. Additional structural information was sought by employing chemical ionization mode. The data generated during this study was instrumented in determining decomposition pathways of CL-20.