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Construction of luminescent high-nuclearity Zn-Ln rectangular nanoclusters with flexible long-chain Schiff base ligands

Three Zn-Ln clusters [Ln Zn (L ) (OAc) (O) (NO ) (OH) ] (Ln = Sm (1) and Nd (2)) and [Nd Zn (L ) (OAc) (NO ) (OH) ] (3) were prepared using two long-chain Schiff base ligands. The Zn-Ln clusters exhibit interesting nano-square-like structures. Their visible and NIR luminescence properties were inves...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (1), p.53-57
Main Authors: Wang, Shiqing, Yang, Xiaoping, Zhu, Ting, Bo, Le, Wang, Ruihu, Huang, Shaoming, Wang, Chengri, Jiang, Dongmei, Chen, Hongfen, Jones, Richard A
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Language:English
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Summary:Three Zn-Ln clusters [Ln Zn (L ) (OAc) (O) (NO ) (OH) ] (Ln = Sm (1) and Nd (2)) and [Nd Zn (L ) (OAc) (NO ) (OH) ] (3) were prepared using two long-chain Schiff base ligands. The Zn-Ln clusters exhibit interesting nano-square-like structures. Their visible and NIR luminescence properties were investigated.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt02576a