Constructing CrIII-centered heterometallic complexes: [Ni6IICrIII] and [Co6IICrIII] wheels

The solvothermal reaction between Cr(acac)3, MCl2·6H2O (M = Ni, Co) and 2-hydroxy-4-methyl-6-phenyl-pyridine-3-amidoxime (H2L), under basic conditions, led to the synthesis of the heterometallic heptanuclear clusters [M6IICr(HLzw)6(HL)6]·3Cl (M = Ni, 1; Co, 2), with the nickel analogue displaying an...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2018-01, Vol.47 (1), p.58-61
Main Authors: Kakaroni, Foteini E, Collet, Alexandra, Sakellari, Eirini, Tzimopoulos, Demetrios I, Siczek, Milosz, Lis, Tadeusz, Murrie, Mark, Milios, Constantinos J
Format: Article
Language:English
Subjects:
Nickel
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Summary:The solvothermal reaction between Cr(acac)3, MCl2·6H2O (M = Ni, Co) and 2-hydroxy-4-methyl-6-phenyl-pyridine-3-amidoxime (H2L), under basic conditions, led to the synthesis of the heterometallic heptanuclear clusters [M6IICr(HLzw)6(HL)6]·3Cl (M = Ni, 1; Co, 2), with the nickel analogue displaying an S = 9/2 spin ground-state.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt04043a