Addition of azomethine ylides to carbon-encapsulated iron nanoparticles

The Prato reaction was applied for the covalent introduction of a variety of organic moieties onto carbon-encapsulated iron nanoparticles. The developed method is versatile and employs a broad range of commercially available reactants, including both aromatic and aliphatic aldehydes. The reported fu...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (1), p.30-34
Main Authors: Kasprzak, Artur, Nowicka, Anna M, Sek, Jakub P, Fronczak, Maciej, Bystrzejewski, Michał, Koszytkowska-Stawinska, Mariola, Poplawska, Magdalena
Format: Article
Language:English
Subjects:
Aldehydes
Aliphatic compounds
Encapsulation
Iron
Nanoparticles
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Summary:The Prato reaction was applied for the covalent introduction of a variety of organic moieties onto carbon-encapsulated iron nanoparticles. The developed method is versatile and employs a broad range of commercially available reactants, including both aromatic and aliphatic aldehydes. The reported functionalization route provides high functionalization yields (ca. 12-21 wt%).
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt03689b