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A green deep eutectic solvent dispersive liquid-liquid micro-extraction (DES-DLLME) for the UHPLC-PDA determination of oxyprenylated phenylpropanoids in olive, soy, peanuts, corn, and sunflower oil

•A green DLLME based on deep eutectic solvents.•A fast UHPLC method coupled with photodiode array detection.•Analysis of oxyprenylated phenylpropanoids in vegetable oils.•Optimization of the DES-DLLME parameters.•The method showed good linearity, limits of detection, and reproducibility. A green dis...

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Bibliographic Details
Published in:Food chemistry 2018-04, Vol.245, p.578-585
Main Authors: Ferrone, Vincenzo, Genovese, Salvatore, Carlucci, Maura, Tiecco, Matteo, Germani, Raimondo, Preziuso, Francesca, Epifano, Francesco, Carlucci, Giuseppe, Taddeo, Vito Alessandro
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Language:English
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Summary:•A green DLLME based on deep eutectic solvents.•A fast UHPLC method coupled with photodiode array detection.•Analysis of oxyprenylated phenylpropanoids in vegetable oils.•Optimization of the DES-DLLME parameters.•The method showed good linearity, limits of detection, and reproducibility. A green dispersive liquid-liquid microextraction (DLLME) using deep eutectic solvent (DES) as the extracting solvent has been developed and applied for the simultaneous quantification of ferulic acid, umbelliferone, boropinic acid, 7-isopentenyloxycoumarin, 4′-geranyloxyferulic acid (GOFA), and auraptene in some vegetable oils using ultra high performance liquid chromatography (UHPLC) with photodiode array detection (PDA). All parameters in the extraction step, including selection and loading of both extracting and dispersing solvents, amount of both extractant and disperser solvent were investigated and optimized. PhAA/TMG DES achieved higher recovery and enrichment factor compared to other DESs. The validated method showed good linearity with correlation coefficients, r2>0.9990 for all the analytes. Furthermore, this is the first time that eco-friendly solvents are used for the extraction of oxyprenylated phenylpropanoids and the corresponding extract analyzed with ultra high performance liquid chromatography with photodiode array detection.
ISSN:0308-8146
1873-7072
DOI:10.1016/j.foodchem.2017.10.135