Relationship between nano/micro structure and physical properties of TiO2-sodium caseinate composite films

• Published in: Food research international 2018-03, Vol.105, p.129-139
• Main Authors: Montes-de-Oca-Ávalos, Juan Manuel, Altamura, Davide, Candal, Roberto Jorge, Scattarella, Francesco, Siliqi, Dritan, Giannini, Cinzia, Herrera, María Lidia
• Format: Article
• Language: English
• Subjects: Conventional emulsion; Gel; Mechanical properties; Nanoemulsions; SAXS/WAXS; Sodium caseinate films; TiO2 nanoparticles; Water vapor permeability
• ISSN: 0963-9969; 1873-7145
• DOI: 10.1016/j.foodres.2017.11.011

Films obtained by casting, starting from conventional emulsions (CE), nanoemulsions (NE) or their gels, which led to different structures, with the aim of explore the relationship between structure and physical properties, were prepared. Sodium caseinate was used as the matrix, glycerol as plasticizer, glucono-delta-lactone as acidulant to form the gels, and TiO2 nanoparticles as reinforcement to improve physical behavior. Structural characterization was performed by SAXS and WAXS (Small and Wide Angle X-ray Scattering, respectively), combined with confocal and scanning electron microscopy. The results demonstrate that the incorporation of the lipid phase does not notably modify the mechanical properties of the films compared to solution films. Films from NE were more stable against oil release than those from CE. Incorporation of TiO2 improved mechanical properties as measured by dynamical mechanical analysis (DMA) and uniaxial tensile tests. TiO2 macroscopic spatial distribution homogeneity and the nanostructure character of NE films were confirmed by mapping the q-dependent scattering intensity in scanning SAXS experiments. SAXS microscopies indicated a higher intrinsic homogeneity of NE films compared to CE films, independently of the TiO2 load. NE-films containing structures with smaller and more homogeneously distributed building blocks showed greater potential for food applications than the films prepared from sodium caseinate solutions, which are the best known films. [Display omitted] •Films from conventional (CE) or nanoemulsions (NE) or their gels were prepared.•Incorporation of the lipid phase did not diminish mechanical or tensile parameters.•Incorporation of TiO2 nanoparticles improved mechanical properties.•Films from NE had a homogeneous structure with nano building blocks.•Homogeneity in structure led to improved physical properties.