Oxidative Dephosphorylation of Benzylic Phosphonates with Dioxygen Generating Symmetrical trans-Stilbenes

Under a dioxygen atmosphere, benzylphosphonates and related phosphoryl compounds can readily produce the corresponding trans-stilbenes in high yields with high selectivity upon treatment with bases. Various functional groups were tolerable under the reaction conditions.

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Bibliographic Details
Published in:Journal of organic chemistry 2018-03, Vol.83 (5), p.2959-2965
Main Authors: Huang, Tianzeng, Chen, Tieqiao, Han, Li-Biao
Format: Article
Language:English
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Description
Summary:Under a dioxygen atmosphere, benzylphosphonates and related phosphoryl compounds can readily produce the corresponding trans-stilbenes in high yields with high selectivity upon treatment with bases. Various functional groups were tolerable under the reaction conditions.
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.7b03148