Cu(II)/Ag(I)-Catalyzed Cascade Reaction of Sulfonylhydrazone with Anthranils: Synthesis of 2‑Aryl-3-sulfonyl Substituted Quinoline Derivatives

In this paper, a Cu­(II)/Ag­(I)-catalyzed cascade reaction of anthranils with sulfonylhydrazone to construct 2-phenyl-3-sulfonyl disubstituted quinoline derivatives under mild conditions was studied. The mechanism study indicated that this reaction involves radical addition, and new C–C, C–N, and C–...

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Bibliographic Details
Published in:Organic letters 2018-04, Vol.20 (8), p.2204-2207
Main Authors: Wang, Fei, Xu, Pei, Wang, Shun-Yi, Ji, Shun-Jun
Format: Article
Language:English
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Summary:In this paper, a Cu­(II)/Ag­(I)-catalyzed cascade reaction of anthranils with sulfonylhydrazone to construct 2-phenyl-3-sulfonyl disubstituted quinoline derivatives under mild conditions was studied. The mechanism study indicated that this reaction involves radical addition, and new C–C, C–N, and C–S bonds were constructed in one step.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.8b00525