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Automated resolution of dichlorvos and methylparaoxon pesticide mixtures employing a Flow Injection system with an inhibition electronic tongue

An amperometric biosensor array has been developed to resolve pesticide mixtures of dichlorvos and methylparaoxon. The biosensor array has been used in a Flow Injection system, in order to operate automatically the inhibition procedure. The sensors used were three screen-printed amperometric biosens...

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Published in:Biosensors & bioelectronics 2009, Vol.24 (5), p.1103-1108
Main Authors: Valdés-Ramírez, G., Gutiérrez, M., del Valle, M., Ramírez-Silva, M.T., Fournier, D., Marty, J.-L.
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cited_by cdi_FETCH-LOGICAL-c415t-a52965944e2358270cd24d91100fc3c64302807e9bc38ddbb7d88755706134c13
cites cdi_FETCH-LOGICAL-c415t-a52965944e2358270cd24d91100fc3c64302807e9bc38ddbb7d88755706134c13
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container_title Biosensors & bioelectronics
container_volume 24
creator Valdés-Ramírez, G.
Gutiérrez, M.
del Valle, M.
Ramírez-Silva, M.T.
Fournier, D.
Marty, J.-L.
description An amperometric biosensor array has been developed to resolve pesticide mixtures of dichlorvos and methylparaoxon. The biosensor array has been used in a Flow Injection system, in order to operate automatically the inhibition procedure. The sensors used were three screen-printed amperometric biosensors that incorporated three different acetylcholinesterase enzymes: the wild type from Electric eel and two different genetically modified enzymes, B1 and B394 mutants, from Drosophila melanogaster. The inhibition response triplet was modelled using an Artificial Neural Network which was trained with mixture solutions that contain dichlorvos from 10 −4 to 0.1 μM and methylparaoxon from 0.001 to 2.5 μM. This system can be considered an inhibition electronic tongue.
doi_str_mv 10.1016/j.bios.2008.06.022
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source Elsevier
subjects Acetylcholinesterase
Acetylcholinesterase - chemistry
Artificial Neural Networks
Bioelectronic tongue
Biological and medical sciences
Biomimetics - instrumentation
Biomimetics - methods
Biosensing Techniques - instrumentation
Biosensing Techniques - methods
Biotechnology
Complex Mixtures - analysis
Dichlorvos
Dichlorvos - analysis
Dichlorvos - chemistry
Drosophila melanogaster
Electrochemistry - instrumentation
Electrochemistry - methods
Electronics - instrumentation
Equipment Design
Equipment Failure Analysis
Flow Injection Analysis
Flow Injection Analysis - instrumentation
Fundamental and applied biological sciences. Psychology
Methylparaoxon
Paraoxon - analogs & derivatives
Paraoxon - analysis
Paraoxon - chemistry
Pesticides - analysis
Reproducibility of Results
Sensitivity and Specificity
Tongue
title Automated resolution of dichlorvos and methylparaoxon pesticide mixtures employing a Flow Injection system with an inhibition electronic tongue
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