Effect of Crosslinker Length and Architecture on the Thermomechanical Properties of CNT‐Loaded Elastomeric Polymer Matrix Composites

• Published in: Macromolecular rapid communications. 2018-07, Vol.39 (14), p.e1800091-n/a
• Main Authors: Wang, Meng, Dheressa, Ermias, Brown, Kristen A., Green, Matthew D.
• Format: Article
• Language: English
• Subjects: Architecture; Bisphenol A; Carbon nanotubes; Crosslinking; Defense industry; Elasticity; elastomeric thermosets; Elastomers; Industrial products; Molecular chains; Molecular weight; Nanocomposites; Nanocomposites - chemistry; Nanotechnology; Nanotubes; Nanotubes, Carbon - chemistry; network; Oxides; Phenols; Polymer matrix composites; polymer nanocomposites; Polymers; Polymers - chemistry; Propylene; Propylene Glycols - chemistry; Storage modulus; Thermodynamics; Thermomechanical properties; Thermosetting resins
• ISSN: 1022-1336; 1521-3927
• DOI: 10.1002/marc.201800091

An evolving understanding of elastomeric polymer nanocomposites continues to expand commercial, defense, and industrial products and applications. This work explores the thermomechanical properties of elastomeric nanocomposites prepared from bisphenol A diglycidyl ether and three amine‐terminated poly(propylene oxides) (Jeffamines). The Jeffamines investigated include difunctional crosslinkers with molecular weights of 2000 and 4000 g mol−1 and a trifunctional crosslinker with a molecular weight of 3000 g mol−1. Additionally, carbon nanotubes (CNTs) are added, up to 1.25 wt%, to each thermoset. The findings indicate that the T g and storage modulus of the polymer nanocomposites can be controlled independently within narrow concentration windows, and that effects observed following CNT incorporation are dependent on the crosslinker molecular weight. Finally, the impact of crosslinker length and architecture as well as CNT addition on the molecular weight between crosslink points in the glassy and rubbery states are discussed. The crosslinker length and architecture as well as carbon nanotube concentration in elastomeric polymer nanocomposites direct the molecular weight between crosslinks, storage modulus, and glass transition temperature. The effect of the nanoparticle addition on the glassy and rubbery state differs; similarly, the impact as a function of crosslinker molecular weight varies.