Bromo‐ and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen‐Rich Halometalate Frameworks

Cation‐dependent reactions “[SbBr6]3−+Br2+HBr+CationBrx” result in the formation of bromide/polybromide complexes with zero‐, one‐, two‐, or three‐dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry : a European journal 2018-07, Vol.24 (40), p.10165-10170
Main Authors: Adonin, Sergey A., Bondarenko, Mikhail A., Abramov, Pavel A., Novikov, Alexander S., Plyusnin, Pavel E., Sokolov, Maxim N., Fedin, Vladimir P.
Format: Article
Language:English
Subjects:
antimony
Cations
Chemistry
DFT calculations
halide complexes
non-covalent interactions
polyhalide
Supramolecular frameworks
Thermogravimetric analysis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c4108-2121f20892874057c71829292245600b90d4d9e8e6330cbc9751260485afb2be3
cites cdi_FETCH-LOGICAL-c4108-2121f20892874057c71829292245600b90d4d9e8e6330cbc9751260485afb2be3
container_end_page 10170
container_issue 40
container_start_page 10165
container_title Chemistry : a European journal
container_volume 24
creator Adonin, Sergey A.
Bondarenko, Mikhail A.
Abramov, Pavel A.
Novikov, Alexander S.
Plyusnin, Pavel E.
Sokolov, Maxim N.
Fedin, Vladimir P.
description Cation‐dependent reactions “[SbBr6]3−+Br2+HBr+CationBrx” result in the formation of bromide/polybromide complexes with zero‐, one‐, two‐, or three‐dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol−1). Capturing more bromine: In the presence of different organic cations, bromoantimonate and polybromide units form hybrid halometalate–polyhalide supramolecular assemblies of different geometries and compositions, “trapping” different numbers of dibromine fragments in the solid state.
doi_str_mv 10.1002/chem.201801338
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2029637893</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2071150647</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4108-2121f20892874057c71829292245600b90d4d9e8e6330cbc9751260485afb2be3</originalsourceid><addsrcrecordid>eNqFkU1P3DAQhq2qCJaPa49VpF6WQ5axncR2b2UFLBKoiI9eI8eZdEOTeGsnQnvjJ_Ab-SV42e1W6qXywZrRM4_seQn5RGFCAdiJmWM7YUAlUM7lBzKiKaMxF1n6kYxAJSLOUq72yL73jwCgMs53yR5TmeSMZiOyPHW2ta_PL5HuyujGNsti1dBdX7e20z368Y_jr9Fd7wbTD04379z9HK3DvjahvuuHskYf2SqaheG6jGa6sT-xC9Lb2szfyxZ73QRbdO50i0_W_fKHZKfSjcejzX1AHs7P7qez-Or7xeX021VsEgoyZpTRioFUTIoEUmEElUyFw5I0AygUlEmpUGL4GZjCKJFSlkEiU10VrEB-QMZr78LZ3wP6Pm9rb7BpdId28DmDsA0upOIB_fIP-mgH14XXBUpQmkKWiEBN1pRx1nuHVb5wdavdMqeQr0LJV6Hk21DCwOeNdihaLLf4nxQCoNbAU93g8j-6fDo7u_4rfwNgVZmJ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2071150647</pqid></control><display><type>article</type><title>Bromo‐ and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen‐Rich Halometalate Frameworks</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Adonin, Sergey A. ; Bondarenko, Mikhail A. ; Abramov, Pavel A. ; Novikov, Alexander S. ; Plyusnin, Pavel E. ; Sokolov, Maxim N. ; Fedin, Vladimir P.</creator><creatorcontrib>Adonin, Sergey A. ; Bondarenko, Mikhail A. ; Abramov, Pavel A. ; Novikov, Alexander S. ; Plyusnin, Pavel E. ; Sokolov, Maxim N. ; Fedin, Vladimir P.</creatorcontrib><description>Cation‐dependent reactions “[SbBr6]3−+Br2+HBr+CationBrx” result in the formation of bromide/polybromide complexes with zero‐, one‐, two‐, or three‐dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol−1). Capturing more bromine: In the presence of different organic cations, bromoantimonate and polybromide units form hybrid halometalate–polyhalide supramolecular assemblies of different geometries and compositions, “trapping” different numbers of dibromine fragments in the solid state.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201801338</identifier><identifier>PMID: 29683216</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>antimony ; Cations ; Chemistry ; DFT calculations ; halide complexes ; non-covalent interactions ; polyhalide ; Supramolecular frameworks ; Thermogravimetric analysis</subject><ispartof>Chemistry : a European journal, 2018-07, Vol.24 (40), p.10165-10170</ispartof><rights>2018 Wiley‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><rights>2018 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4108-2121f20892874057c71829292245600b90d4d9e8e6330cbc9751260485afb2be3</citedby><cites>FETCH-LOGICAL-c4108-2121f20892874057c71829292245600b90d4d9e8e6330cbc9751260485afb2be3</cites><orcidid>0000-0002-9889-5273</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29683216$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Adonin, Sergey A.</creatorcontrib><creatorcontrib>Bondarenko, Mikhail A.</creatorcontrib><creatorcontrib>Abramov, Pavel A.</creatorcontrib><creatorcontrib>Novikov, Alexander S.</creatorcontrib><creatorcontrib>Plyusnin, Pavel E.</creatorcontrib><creatorcontrib>Sokolov, Maxim N.</creatorcontrib><creatorcontrib>Fedin, Vladimir P.</creatorcontrib><title>Bromo‐ and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen‐Rich Halometalate Frameworks</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>Cation‐dependent reactions “[SbBr6]3−+Br2+HBr+CationBrx” result in the formation of bromide/polybromide complexes with zero‐, one‐, two‐, or three‐dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol−1). Capturing more bromine: In the presence of different organic cations, bromoantimonate and polybromide units form hybrid halometalate–polyhalide supramolecular assemblies of different geometries and compositions, “trapping” different numbers of dibromine fragments in the solid state.</description><subject>antimony</subject><subject>Cations</subject><subject>Chemistry</subject><subject>DFT calculations</subject><subject>halide complexes</subject><subject>non-covalent interactions</subject><subject>polyhalide</subject><subject>Supramolecular frameworks</subject><subject>Thermogravimetric analysis</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkU1P3DAQhq2qCJaPa49VpF6WQ5axncR2b2UFLBKoiI9eI8eZdEOTeGsnQnvjJ_Ab-SV42e1W6qXywZrRM4_seQn5RGFCAdiJmWM7YUAlUM7lBzKiKaMxF1n6kYxAJSLOUq72yL73jwCgMs53yR5TmeSMZiOyPHW2ta_PL5HuyujGNsti1dBdX7e20z368Y_jr9Fd7wbTD04379z9HK3DvjahvuuHskYf2SqaheG6jGa6sT-xC9Lb2szfyxZ73QRbdO50i0_W_fKHZKfSjcejzX1AHs7P7qez-Or7xeX021VsEgoyZpTRioFUTIoEUmEElUyFw5I0AygUlEmpUGL4GZjCKJFSlkEiU10VrEB-QMZr78LZ3wP6Pm9rb7BpdId28DmDsA0upOIB_fIP-mgH14XXBUpQmkKWiEBN1pRx1nuHVb5wdavdMqeQr0LJV6Hk21DCwOeNdihaLLf4nxQCoNbAU93g8j-6fDo7u_4rfwNgVZmJ</recordid><startdate>20180717</startdate><enddate>20180717</enddate><creator>Adonin, Sergey A.</creator><creator>Bondarenko, Mikhail A.</creator><creator>Abramov, Pavel A.</creator><creator>Novikov, Alexander S.</creator><creator>Plyusnin, Pavel E.</creator><creator>Sokolov, Maxim N.</creator><creator>Fedin, Vladimir P.</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-9889-5273</orcidid></search><sort><creationdate>20180717</creationdate><title>Bromo‐ and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen‐Rich Halometalate Frameworks</title><author>Adonin, Sergey A. ; Bondarenko, Mikhail A. ; Abramov, Pavel A. ; Novikov, Alexander S. ; Plyusnin, Pavel E. ; Sokolov, Maxim N. ; Fedin, Vladimir P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4108-2121f20892874057c71829292245600b90d4d9e8e6330cbc9751260485afb2be3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>antimony</topic><topic>Cations</topic><topic>Chemistry</topic><topic>DFT calculations</topic><topic>halide complexes</topic><topic>non-covalent interactions</topic><topic>polyhalide</topic><topic>Supramolecular frameworks</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Adonin, Sergey A.</creatorcontrib><creatorcontrib>Bondarenko, Mikhail A.</creatorcontrib><creatorcontrib>Abramov, Pavel A.</creatorcontrib><creatorcontrib>Novikov, Alexander S.</creatorcontrib><creatorcontrib>Plyusnin, Pavel E.</creatorcontrib><creatorcontrib>Sokolov, Maxim N.</creatorcontrib><creatorcontrib>Fedin, Vladimir P.</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health &amp; Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adonin, Sergey A.</au><au>Bondarenko, Mikhail A.</au><au>Abramov, Pavel A.</au><au>Novikov, Alexander S.</au><au>Plyusnin, Pavel E.</au><au>Sokolov, Maxim N.</au><au>Fedin, Vladimir P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bromo‐ and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen‐Rich Halometalate Frameworks</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2018-07-17</date><risdate>2018</risdate><volume>24</volume><issue>40</issue><spage>10165</spage><epage>10170</epage><pages>10165-10170</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>Cation‐dependent reactions “[SbBr6]3−+Br2+HBr+CationBrx” result in the formation of bromide/polybromide complexes with zero‐, one‐, two‐, or three‐dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol−1). Capturing more bromine: In the presence of different organic cations, bromoantimonate and polybromide units form hybrid halometalate–polyhalide supramolecular assemblies of different geometries and compositions, “trapping” different numbers of dibromine fragments in the solid state.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>29683216</pmid><doi>10.1002/chem.201801338</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-9889-5273</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0947-6539
ispartof Chemistry : a European journal, 2018-07, Vol.24 (40), p.10165-10170
issn 0947-6539
1521-3765
language eng
recordid cdi_proquest_miscellaneous_2029637893
source Wiley-Blackwell Read & Publish Collection
subjects antimony
Cations
Chemistry
DFT calculations
halide complexes
non-covalent interactions
polyhalide
Supramolecular frameworks
Thermogravimetric analysis
title Bromo‐ and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen‐Rich Halometalate Frameworks
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T19%3A26%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Bromo%E2%80%90%20and%20Polybromoantimonates(V):%20Structural%20and%20Theoretical%20Studies%20of%20Hybrid%20Halogen%E2%80%90Rich%20Halometalate%20Frameworks&rft.jtitle=Chemistry%20:%20a%20European%20journal&rft.au=Adonin,%20Sergey%20A.&rft.date=2018-07-17&rft.volume=24&rft.issue=40&rft.spage=10165&rft.epage=10170&rft.pages=10165-10170&rft.issn=0947-6539&rft.eissn=1521-3765&rft_id=info:doi/10.1002/chem.201801338&rft_dat=%3Cproquest_cross%3E2071150647%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c4108-2121f20892874057c71829292245600b90d4d9e8e6330cbc9751260485afb2be3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2071150647&rft_id=info:pmid/29683216&rfr_iscdi=true