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Mechanical and moisture barrier properties of corn distarch phosphate film influenced by modified microcry stalline corn straw cellulose
BACKGROUND In this paper, a novel modified microcrystalline corn straw cellulose (MMCSC) was prepared by ultrasonic/microwave‐assisted treatment. Effective incorporation of MMCSC into corn distarch phosphate (CDP)‐based composite films was investigated. RESULTS As the proportion of MMCSC was increas...
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Published in: | Journal of the science of food and agriculture 2018-12, Vol.98 (15), p.5639-5646 |
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creator | Shao, Xinru Sun, Haitao Jiang, Ruiping Qin, Ting Ma, Zhongsu |
description | BACKGROUND
In this paper, a novel modified microcrystalline corn straw cellulose (MMCSC) was prepared by ultrasonic/microwave‐assisted treatment. Effective incorporation of MMCSC into corn distarch phosphate (CDP)‐based composite films was investigated.
RESULTS
As the proportion of MMCSC was increased, tensile strength increased initially before decreasing, and the elongation at break always decreased. The composite film of MMCSC20 showed the lowest water vapor permeability (2.917 × 10−7 g m−1 h−1 Pa−1). The measurement of surface color showed that by the increasing of the MMCSC proportion in composite films, the L* and b* values and the total color difference (ΔE*) increased, while a* values decreased. Fourier transform infrared spectroscopy and X‐ray diffraction analysis indicated that, with the incorporation of MMCSC, the stable structure of the films was enhanced through cross‐linking and the crystallinity was increased. A scanning electron microscopy study revealed the surface microstructure of films (MMCSC0–MMCSC30) was smooth and homogeneous, and there was no distinct separation in the matrix of composite films.
CONCLUSION
The incorporation of suitable MMCSC could improve the properties of composite films. The CDP–MMCSC films, which are completely biodegradable and environmental friendly, have a high potential to be used for food packaging. © 2018 Society of Chemical Industry |
doi_str_mv | 10.1002/jsfa.9109 |
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In this paper, a novel modified microcrystalline corn straw cellulose (MMCSC) was prepared by ultrasonic/microwave‐assisted treatment. Effective incorporation of MMCSC into corn distarch phosphate (CDP)‐based composite films was investigated.
RESULTS
As the proportion of MMCSC was increased, tensile strength increased initially before decreasing, and the elongation at break always decreased. The composite film of MMCSC20 showed the lowest water vapor permeability (2.917 × 10−7 g m−1 h−1 Pa−1). The measurement of surface color showed that by the increasing of the MMCSC proportion in composite films, the L* and b* values and the total color difference (ΔE*) increased, while a* values decreased. Fourier transform infrared spectroscopy and X‐ray diffraction analysis indicated that, with the incorporation of MMCSC, the stable structure of the films was enhanced through cross‐linking and the crystallinity was increased. A scanning electron microscopy study revealed the surface microstructure of films (MMCSC0–MMCSC30) was smooth and homogeneous, and there was no distinct separation in the matrix of composite films.
CONCLUSION
The incorporation of suitable MMCSC could improve the properties of composite films. The CDP–MMCSC films, which are completely biodegradable and environmental friendly, have a high potential to be used for food packaging. © 2018 Society of Chemical Industry</description><identifier>ISSN: 0022-5142</identifier><identifier>EISSN: 1097-0010</identifier><identifier>DOI: 10.1002/jsfa.9109</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>Biodegradability ; biodegradable ; Biodegradation ; Cellulose ; Color ; composite ; Corn ; Corn straw ; crystallization ; Elongation ; Food packaging ; Food packaging industry ; Fourier transforms ; Infrared analysis ; Infrared spectroscopy ; Organic chemistry ; Permeability ; Phosphates ; properties and characterization ; Scanning electron microscopy ; Straw ; Water vapor ; X ray spectra ; X-ray diffraction</subject><ispartof>Journal of the science of food and agriculture, 2018-12, Vol.98 (15), p.5639-5646</ispartof><rights>2018 Society of Chemical Industry</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3309-6a78415f7710122aa9628767552de71fa9a48d28a335ee80cf393289b5b1db733</citedby><cites>FETCH-LOGICAL-c3309-6a78415f7710122aa9628767552de71fa9a48d28a335ee80cf393289b5b1db733</cites><orcidid>0000-0002-5978-7720</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Shao, Xinru</creatorcontrib><creatorcontrib>Sun, Haitao</creatorcontrib><creatorcontrib>Jiang, Ruiping</creatorcontrib><creatorcontrib>Qin, Ting</creatorcontrib><creatorcontrib>Ma, Zhongsu</creatorcontrib><title>Mechanical and moisture barrier properties of corn distarch phosphate film influenced by modified microcry stalline corn straw cellulose</title><title>Journal of the science of food and agriculture</title><description>BACKGROUND
In this paper, a novel modified microcrystalline corn straw cellulose (MMCSC) was prepared by ultrasonic/microwave‐assisted treatment. Effective incorporation of MMCSC into corn distarch phosphate (CDP)‐based composite films was investigated.
RESULTS
As the proportion of MMCSC was increased, tensile strength increased initially before decreasing, and the elongation at break always decreased. The composite film of MMCSC20 showed the lowest water vapor permeability (2.917 × 10−7 g m−1 h−1 Pa−1). The measurement of surface color showed that by the increasing of the MMCSC proportion in composite films, the L* and b* values and the total color difference (ΔE*) increased, while a* values decreased. Fourier transform infrared spectroscopy and X‐ray diffraction analysis indicated that, with the incorporation of MMCSC, the stable structure of the films was enhanced through cross‐linking and the crystallinity was increased. A scanning electron microscopy study revealed the surface microstructure of films (MMCSC0–MMCSC30) was smooth and homogeneous, and there was no distinct separation in the matrix of composite films.
CONCLUSION
The incorporation of suitable MMCSC could improve the properties of composite films. The CDP–MMCSC films, which are completely biodegradable and environmental friendly, have a high potential to be used for food packaging. © 2018 Society of Chemical Industry</description><subject>Biodegradability</subject><subject>biodegradable</subject><subject>Biodegradation</subject><subject>Cellulose</subject><subject>Color</subject><subject>composite</subject><subject>Corn</subject><subject>Corn straw</subject><subject>crystallization</subject><subject>Elongation</subject><subject>Food packaging</subject><subject>Food packaging industry</subject><subject>Fourier transforms</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Organic chemistry</subject><subject>Permeability</subject><subject>Phosphates</subject><subject>properties and characterization</subject><subject>Scanning electron microscopy</subject><subject>Straw</subject><subject>Water vapor</subject><subject>X ray spectra</subject><subject>X-ray diffraction</subject><issn>0022-5142</issn><issn>1097-0010</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kc9q3DAQxkVoIdu0h7yBoJfm4ER_1pZ1XEKTtGzpIelZjOURq0W2XMkm7BvksaPN9hToZWZgfvMxMx8hl5xdc8bEzT47uNac6TOyKlFVjHH2gaxKT1Q1X4tz8innPWNM66ZZkZdfaHcweguBwtjTIfo8LwlpByl5THRKccI0e8w0OmpjGmlfEEh2R6ddzNMOZqTOh4H60YUFR4s97Q5FqffOl3rwNkWbDrRMheBHPKnkOcEztRjCEmLGz-Sjg5Dxy798Qf7cfX-6fai2v-9_3G62lZWS6aoB1a557ZTijAsBoBvRqkbVtehRcQca1m0vWpCyRmyZdVJL0equ7njfKSkvyLeTbjns74J5NoPPxy1gxLhkI5gUStd63RT06zt0H5c0lu2M4JI3UpevFurqRJUrc07ozJT8AOlgODNHT8zRE3P0pLA3J_bZBzz8HzQ_H-82bxOvIGSP1A</recordid><startdate>201812</startdate><enddate>201812</enddate><creator>Shao, Xinru</creator><creator>Sun, Haitao</creator><creator>Jiang, Ruiping</creator><creator>Qin, Ting</creator><creator>Ma, Zhongsu</creator><general>John Wiley & Sons, Ltd</general><general>John Wiley and Sons, Limited</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QL</scope><scope>7QQ</scope><scope>7QR</scope><scope>7SC</scope><scope>7SE</scope><scope>7SN</scope><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7T5</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7TM</scope><scope>7U5</scope><scope>7U9</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>M7N</scope><scope>P64</scope><scope>SOI</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5978-7720</orcidid></search><sort><creationdate>201812</creationdate><title>Mechanical and moisture barrier properties of corn distarch phosphate film influenced by modified microcry stalline corn straw cellulose</title><author>Shao, Xinru ; Sun, Haitao ; Jiang, Ruiping ; Qin, Ting ; Ma, Zhongsu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3309-6a78415f7710122aa9628767552de71fa9a48d28a335ee80cf393289b5b1db733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Biodegradability</topic><topic>biodegradable</topic><topic>Biodegradation</topic><topic>Cellulose</topic><topic>Color</topic><topic>composite</topic><topic>Corn</topic><topic>Corn straw</topic><topic>crystallization</topic><topic>Elongation</topic><topic>Food packaging</topic><topic>Food packaging industry</topic><topic>Fourier transforms</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Organic chemistry</topic><topic>Permeability</topic><topic>Phosphates</topic><topic>properties and characterization</topic><topic>Scanning electron microscopy</topic><topic>Straw</topic><topic>Water vapor</topic><topic>X ray spectra</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shao, Xinru</creatorcontrib><creatorcontrib>Sun, Haitao</creatorcontrib><creatorcontrib>Jiang, Ruiping</creatorcontrib><creatorcontrib>Qin, Ting</creatorcontrib><creatorcontrib>Ma, Zhongsu</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ceramic Abstracts</collection><collection>Chemoreception Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Ecology Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Immunology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the science of food and agriculture</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shao, Xinru</au><au>Sun, Haitao</au><au>Jiang, Ruiping</au><au>Qin, Ting</au><au>Ma, Zhongsu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanical and moisture barrier properties of corn distarch phosphate film influenced by modified microcry stalline corn straw cellulose</atitle><jtitle>Journal of the science of food and agriculture</jtitle><date>2018-12</date><risdate>2018</risdate><volume>98</volume><issue>15</issue><spage>5639</spage><epage>5646</epage><pages>5639-5646</pages><issn>0022-5142</issn><eissn>1097-0010</eissn><abstract>BACKGROUND
In this paper, a novel modified microcrystalline corn straw cellulose (MMCSC) was prepared by ultrasonic/microwave‐assisted treatment. Effective incorporation of MMCSC into corn distarch phosphate (CDP)‐based composite films was investigated.
RESULTS
As the proportion of MMCSC was increased, tensile strength increased initially before decreasing, and the elongation at break always decreased. The composite film of MMCSC20 showed the lowest water vapor permeability (2.917 × 10−7 g m−1 h−1 Pa−1). The measurement of surface color showed that by the increasing of the MMCSC proportion in composite films, the L* and b* values and the total color difference (ΔE*) increased, while a* values decreased. Fourier transform infrared spectroscopy and X‐ray diffraction analysis indicated that, with the incorporation of MMCSC, the stable structure of the films was enhanced through cross‐linking and the crystallinity was increased. A scanning electron microscopy study revealed the surface microstructure of films (MMCSC0–MMCSC30) was smooth and homogeneous, and there was no distinct separation in the matrix of composite films.
CONCLUSION
The incorporation of suitable MMCSC could improve the properties of composite films. The CDP–MMCSC films, which are completely biodegradable and environmental friendly, have a high potential to be used for food packaging. © 2018 Society of Chemical Industry</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/jsfa.9109</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-5978-7720</orcidid></addata></record> |
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subjects | Biodegradability biodegradable Biodegradation Cellulose Color composite Corn Corn straw crystallization Elongation Food packaging Food packaging industry Fourier transforms Infrared analysis Infrared spectroscopy Organic chemistry Permeability Phosphates properties and characterization Scanning electron microscopy Straw Water vapor X ray spectra X-ray diffraction |
title | Mechanical and moisture barrier properties of corn distarch phosphate film influenced by modified microcry stalline corn straw cellulose |
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