Cation-Induced Macroscopic Ordering of Non-Mesomorphic Modules-A New Application for Metallohelicates

The subtle balance between organized and chaotic domains in the nondiscoidal ligand in the helicate 1, which displays liquid crystalline properties, represents the key element which enables the local molecular architecture to be integrated into an organized macroscopic ensemble.

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Bibliographic Details
Published in:Angewandte Chemie International Edition 1998-09, Vol.37 (16), p.2205-2208
Main Authors: El-ghayoury, Abdelkrim, Douce, Laurent, Skoulios, Antoine, Ziessel, Raymond
Format: Article
Language:English
Subjects:
Copper
Helical structures
Metallomesogens
N ligands
Supramolecular chemistry
Online Access:Get full text
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Description
Summary:The subtle balance between organized and chaotic domains in the nondiscoidal ligand in the helicate 1, which displays liquid crystalline properties, represents the key element which enables the local molecular architecture to be integrated into an organized macroscopic ensemble.
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19980904)37:16<2205::AID-ANIE2205>3.0.CO;2-R